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Characterization of traditional artificial patinas on copper using the voltammetry of immobilized particles

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Characterization of traditional artificial patinas on copper using the voltammetry of immobilized particles

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dc.contributor.author Doménech-Carbó, Antonio es_ES
dc.contributor.author Ramírez-Barat, Blanca es_ES
dc.contributor.author Petiti, Chiara es_ES
dc.contributor.author Goidianich, Sara es_ES
dc.contributor.author Domenech Carbo, Mª Teresa es_ES
dc.contributor.author Cano, Emilio es_ES
dc.date.accessioned 2021-09-14T03:33:07Z
dc.date.available 2021-09-14T03:33:07Z
dc.date.issued 2020-11-15 es_ES
dc.identifier.issn 1572-6657 es_ES
dc.identifier.uri http://hdl.handle.net/10251/172299
dc.description.abstract [EN] The voltammetry of immobilized particles methodology (VIMP) is used to characterize the composition of artificial patinas on copper. The voltammetric response of carbonate-, nitrate-, chloride-, sulfate-, and sulfide-based patinas is described using sub-microsamples attached to graphite electrodes in contact with aqueous acetate buffer. Patina-characteristic voltammetric profiles are obtained for the different artificial patinas that can be recognized using the generalized Tafel analysis of the voltammetric curves. VIMP data could also provide layer-by-layer information about composition and compactness/crystallinity of the patinas for which a simplified theoretical modeling is presented. es_ES
dc.description.sponsorship Authors gratefully acknowledge funding from Project CTQ2017-85317-C2-1-P, supported with Ministerio de Economia, Industria y Competitividad (MINECO), Fondo Europeo de Desarrollo Regional (ERDF) and Agencia Estatal de Investigacion (AEI); and project TOP-HERITAGE CM (S2018/NMT_4372) from Comunidad de Madrid and European Structural and Investment Funds. B. R.-B. and E.C. would like to professional support of the CSIC Interdisciplinary Thematic Platform "Open Heritage: Research and Society" (PTI-PAIS). es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Electroanalytical Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Electrochemistry es_ES
dc.subject Artificial patinas es_ES
dc.subject Copper es_ES
dc.subject Bronze es_ES
dc.subject.classification PINTURA es_ES
dc.title Characterization of traditional artificial patinas on copper using the voltammetry of immobilized particles es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.jelechem.2020.114494 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAM//S2018%2NMT-4372/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-85317-C2-1-P/ES/APLICACION DE TECNICAS AVANZADAS DE MICROSCOPIA EN EL ESTUDIO DEL PATRIMONIO CERAMICO Y VITREO/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Conservación y Restauración de Bienes Culturales - Departament de Conservació i Restauració de Béns Culturals es_ES
dc.description.bibliographicCitation Doménech-Carbó, A.; Ramírez-Barat, B.; Petiti, C.; Goidianich, S.; Domenech Carbo, MT.; Cano, E. (2020). Characterization of traditional artificial patinas on copper using the voltammetry of immobilized particles. Journal of Electroanalytical Chemistry. 877:1-9. https://doi.org/10.1016/j.jelechem.2020.114494 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.jelechem.2020.114494 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 877 es_ES
dc.relation.pasarela S\434327 es_ES
dc.contributor.funder Comunidad de Madrid es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
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