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Solid-state electrochemical characterization of emissions and authorities producing Roman brass coins

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Solid-state electrochemical characterization of emissions and authorities producing Roman brass coins

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dc.contributor.author Di Fazio, Melania es_ES
dc.contributor.author Felici, Anna Candida es_ES
dc.contributor.author Catalli, Fiorenzo es_ES
dc.contributor.author Domenech Carbo, Mª Teresa es_ES
dc.contributor.author De Vito, Caterina es_ES
dc.contributor.author Doménech-Carbó, Antonio es_ES
dc.date.accessioned 2021-09-14T03:33:37Z
dc.date.available 2021-09-14T03:33:37Z
dc.date.issued 2020-01 es_ES
dc.identifier.issn 0026-265X es_ES
dc.identifier.uri http://hdl.handle.net/10251/172315
dc.description.abstract [EN] The voltammetry of immobilized particles (VIMP) is applied to describe the solid state electrochemistry of brass. This methodology, which involves sampling at the nanogram level, is applied to discriminate mints/authorities producing different Roman monetary emissions covering since the Republic (88 BCE) to Domitianus (55-96 CE) Upon attachment to graphite electrodes in contact with aqueous acetate buffer at pH 4.75, well defined voltarnmetric responses were obtained centered on Cu- and Zn-localized signals whose intensity can be correlated to EMP data, being sensitive to the contents of Zn (15-30 wt.%) and Sn (0.01-1.1 wt.%). Voltammetric data, combined with ATR-FTIR and FIB-PESEM/EDS, yield information on the structure of the metal patina and permit to characterize different monetary emissions being able, in the case of Augustus' sestertii, to discriminate between the productions from different monetary authorities. es_ES
dc.description.sponsorship Financial support is gratefully acknowledged from the Spanish "R + D +I" project CTQ2017-85317-C2-1-P, CTQ2014-53736-C3-1-P and CTQ2014-53736-C3-2-P, which are supported by the Ministerio de Glenda, Innovacion y Universidades, Fondo Europeo de Desarrollo Regional (ERDF) funds and Agenda Estatal de Investigacion (AEI). The authors wish to thank Mr. Manuel Planes, Dr. Jose Luis Moya and Mrs. Alicia Nuez Inberrion, technical supervisors of the Electron Microscopy Service of the Universitat Politecnica de Valencia. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation MINECO/CTQ2014-53736-C3-2-P es_ES
dc.relation MINECO/CTQ2014-53736-C3-1-P es_ES
dc.relation.ispartof Microchemical Journal es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Orichalcum es_ES
dc.subject Roman coins es_ES
dc.subject Voltammetry es_ES
dc.subject Archaeometry es_ES
dc.subject.classification PINTURA es_ES
dc.title Solid-state electrochemical characterization of emissions and authorities producing Roman brass coins es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.microc.2019.104306 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-85317-C2-1-P/ES/APLICACION DE TECNICAS AVANZADAS DE MICROSCOPIA EN EL ESTUDIO DEL PATRIMONIO CERAMICO Y VITREO/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Conservación y Restauración de Bienes Culturales - Departament de Conservació i Restauració de Béns Culturals es_ES
dc.description.bibliographicCitation Di Fazio, M.; Felici, AC.; Catalli, F.; Domenech Carbo, MT.; De Vito, C.; Doménech-Carbó, A. (2020). Solid-state electrochemical characterization of emissions and authorities producing Roman brass coins. Microchemical Journal. 152:1-9. https://doi.org/10.1016/j.microc.2019.104306 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.microc.2019.104306 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 152 es_ES
dc.relation.pasarela S\423714 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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