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Confining isolated atoms and clusters in crystalline porous materials for catalysis

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dc.contributor.author Liu, Lichen es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2022-11-10T19:02:27Z
dc.date.available 2022-11-10T19:02:27Z
dc.date.issued 2021-03 es_ES
dc.identifier.uri http://hdl.handle.net/10251/189595
dc.description.abstract [EN] Structure-reactivity relationships for nanoparticle-based catalysts have been greatly influenced by the study of catalytic materials with either supported isolated metal atoms or metal clusters comprising a few atoms. The stability of these metal species is a key challenge because they can sinter into large nanoparticles under harsh reaction conditions. However, stability can be achieved by confining the nanoparticles in crystalline porous materials (such as zeolites and metal-organic frameworks). More importantly, the interaction between the metal species and the porous framework may modulate the geometric and electronic structures of the subnanometric metal species, especially for metal clusters. This confinement effect can induce shape-selective catalysis or different chemoselectivity from that of metal atoms supported on open-structure solid carriers. In this Review, we discuss the structural features, synthesis methodologies, characterization techniques and catalytic applications of subnanometric species confined in zeolites and metal-organic frameworks. We make a critical comparison between confined and non-confined isolated atoms and metal clusters, and provide future perspectives for the field. es_ES
dc.description.sponsorship We are grateful for financial support from the European Research Council (grant ERC-AdG-2014-671093, SynCatMatch) and the Spanish Government through the Severo Ochoa Program (SEV-2016-0683). es_ES
dc.language Inglés es_ES
dc.publisher Nature Publishing Group es_ES
dc.relation.ispartof Nature Reviews Materials es_ES
dc.rights Reserva de todos los derechos es_ES
dc.title Confining isolated atoms and clusters in crystalline porous materials for catalysis es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1038/s41578-020-00250-3 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683//Programa Estatal de Fomento de la Investigación Científica y Técnica de Excelencia/ es_ES
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Liu, L.; Corma Canós, A. (2021). Confining isolated atoms and clusters in crystalline porous materials for catalysis. Nature Reviews Materials. 6(3):244-263. https://doi.org/10.1038/s41578-020-00250-3 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1038/s41578-020-00250-3 es_ES
dc.description.upvformatpinicio 244 es_ES
dc.description.upvformatpfin 263 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 6 es_ES
dc.description.issue 3 es_ES
dc.identifier.eissn 2058-8437 es_ES
dc.relation.pasarela S\463095 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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