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Synthesis of Gold Nanoparticles and Incorporation to a Porous Nickel Electrode to Improve its Catalytic Performance Towards the Hydrogen Evolution Reaction

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Synthesis of Gold Nanoparticles and Incorporation to a Porous Nickel Electrode to Improve its Catalytic Performance Towards the Hydrogen Evolution Reaction

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dc.contributor.author Medina-Orta, Ramiro es_ES
dc.contributor.author Labrada-Delgado, Gladis J. es_ES
dc.contributor.author Silva-Pereyra, Héctor G. es_ES
dc.contributor.author Ortega Navarro, Emma María es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.contributor.author Sánchez-Loredo, María Guadalupe es_ES
dc.date.accessioned 2023-05-17T18:01:00Z
dc.date.available 2023-05-17T18:01:00Z
dc.date.issued 2022-01 es_ES
dc.identifier.issn 1868-2529 es_ES
dc.identifier.uri http://hdl.handle.net/10251/193458
dc.description.abstract [EN] Gold nanoparticles (AuNPs) were successfully synthesized by a facile chemical reduction method in the presence of the stabilizer polyvinylpyrrolidone and characterized by UV-vis spectroscopy and transmission electron microscopy. The gold nanoparticles were then incorporated onto the surface of a porous Ni electrode by simple addition of the nanoparticles suspension, followed by heat treatment at 350 degrees C for 1 h under nitrogen atmosphere. The modified electrode was morphologically characterized by field emission scanning electron microscopy. Then, the effect of the modification with Au nanoparticles was studied in the hydrogen evolution reaction (HER) by pseudo-steady-state polarization curves and electrochemical impedance spectroscopy (EIS), at different temperatures and compared with a pure porous Ni electrode. The modified electrode showed a clear improvement in its catalytic performance mainly due to the intrinsic catalytic activity of the Au nanoparticles. From the Tafel representations and the EIS, it was estimated that the HER on the electrode modified with AuNPs takes place by the Volmer-Heyrovsky mechanism. es_ES
dc.description.sponsorship Ramiro Medina Orta is grateful to Consejo Nacional Ciencia y Tecnologia and Consejo Potosino de Ciencia y Tecnologia for the doctorate scholarship 472041. Also, he wishes to thank the Instituto de Metalurgia of Universidad Autonoma de San Luis Potosi for the opportunity of a research stay. We also thank Dr. Nubia Arteaga Larios and M.M.I.M. Martha Alejandra Lomeli Pacheco (Instituto de Metalurgia, Universidad Autonoma de San Luis Potosi) for their help with the UV-vis spectroscopy. es_ES
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Electrocatalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Porous Ni electrodes es_ES
dc.subject Au nanoparticles es_ES
dc.subject Chemical synthesis es_ES
dc.subject Hydrogen evolution reaction (HER) es_ES
dc.subject Catalysis es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Synthesis of Gold Nanoparticles and Incorporation to a Porous Nickel Electrode to Improve its Catalytic Performance Towards the Hydrogen Evolution Reaction es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s12678-021-00690-7 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/COPOCYT//472041/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials es_ES
dc.description.bibliographicCitation Medina-Orta, R.; Labrada-Delgado, GJ.; Silva-Pereyra, HG.; Ortega Navarro, EM.; Pérez-Herranz, V.; Sánchez-Loredo, MG. (2022). Synthesis of Gold Nanoparticles and Incorporation to a Porous Nickel Electrode to Improve its Catalytic Performance Towards the Hydrogen Evolution Reaction. Electrocatalysis. 13(1):47-61. https://doi.org/10.1007/s12678-021-00690-7 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1007/s12678-021-00690-7 es_ES
dc.description.upvformatpinicio 47 es_ES
dc.description.upvformatpfin 61 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 13 es_ES
dc.description.issue 1 es_ES
dc.relation.pasarela S\467593 es_ES
dc.contributor.funder Consejo Potosino de Ciencia y Tecnología es_ES
dc.contributor.funder Consejo Nacional de Ciencia y Tecnología, México es_ES
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dc.subject.ods 07.- Asegurar el acceso a energías asequibles, fiables, sostenibles y modernas para todos es_ES


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