Turner, GF.; Campbell, F.; Moggach, SA.; Parsons, S.; Goeta, AE.; Muñoz Roca, MDC.; Real, JA. (2020). Single-Crystal X-Ray Diffraction Study of Pressure and Temperature-Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework. Angewandte Chemie International Edition. 59(8):3106-3111. https://doi.org/10.1002/anie.201914360
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/193484
Título:
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Single-Crystal X-Ray Diffraction Study of Pressure and Temperature-Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework
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Autor:
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Turner, Gemma F.
Campbell, Fallyn
Moggach, Stephen A.
Parsons, Simon
Goeta, Andrés E.
Muñoz Roca, María Del Carmen
Real, José A.
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Entidad UPV:
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Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny
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Fecha difusión:
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Resumen:
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[EN] High-pressure single-crystal X-ray diffraction has been used to trap both the low-spin (LS) and high-spin (HS) states of the iron(II) Hofmann spin crossover framework, [FeII (pdm)(H2 O)[Ag(CN)2 ]2·H2 O, under identical ...[+]
[EN] High-pressure single-crystal X-ray diffraction has been used to trap both the low-spin (LS) and high-spin (HS) states of the iron(II) Hofmann spin crossover framework, [FeII (pdm)(H2 O)[Ag(CN)2 ]2·H2 O, under identical experimental conditions, allowing the structural changes arising from the spin-transition to be deconvoluted from previously reported thermal effects.
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Derechos de uso:
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Reserva de todos los derechos
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Fuente:
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Angewandte Chemie International Edition. (issn:
1433-7851
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DOI:
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10.1002/anie.201914360
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Editorial:
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John Wiley & Sons
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Versión del editor:
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https://doi.org/10.1002/anie.201914360
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Código del Proyecto:
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info:eu-repo/grantAgreement/MINECO//BIO2014-60538-JIN/ES/PEPTIDOS PENETRADORES DE CELULAS: NUEVAS HERRAMIENTAS EN LA OPTIMIZACION QUIMIOTERAPEUTICA EN TRIPANOSOMATIDOS/
...[+]
info:eu-repo/grantAgreement/MINECO//BIO2014-60538-JIN/ES/PEPTIDOS PENETRADORES DE CELULAS: NUEVAS HERRAMIENTAS EN LA OPTIMIZACION QUIMIOTERAPEUTICA EN TRIPANOSOMATIDOS/
info:eu-repo/grantAgreement/Generalitat Valenciana//PROMETEO2016%2F147//Sensores y memorias moleculares basados en materiales biestables que presentan transición de espín/
info:eu-repo/grantAgreement/Ministerio de Economía, Industria y Competitividad (MINECO)//CTQ2016-78341-P//Materiales spin srossover biestables: de las propiedades macroscópicas a la espintrónica molecular/
info:eu-repo/grantAgreement/EPSRC//GR%2FM81830/
info:eu-repo/grantAgreement/EPSRC//EP%2FD503744/
info:eu-repo/grantAgreement/MINECO//MDM-2015-0538//INSTITUTO DE CIENCIA MOLECULAR/
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Descripción:
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This is the peer reviewed version of the following article: Turner, G. F., Campbell, F., Moggach, S. A., Parsons, S., Goeta, A. E., Muñoz, M. C., & Real, J. A. (2020). Single-Crystal X-Ray Diffraction Study of Pressure and Temperature¿Induced Spin Trapping in a Bistable Iron (II) Hofmann Framework. Angewandte Chemie International Edition, 59(8), 3106-3111, which has been published in final form at https://doi.org/10.1002/anie.201914360. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."
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Agradecimientos:
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This work was supported by the Spanish Ministerio de Economia y Competitividad (MINECO), FEDER (CTQ2016-78341-P), Unidad de Excelencia Mar&a de Maeztu (MDM 2015-0538), the Generalitat Valenciana through PROMETEO/2016/147, ...[+]
This work was supported by the Spanish Ministerio de Economia y Competitividad (MINECO), FEDER (CTQ2016-78341-P), Unidad de Excelencia Mar&a de Maeztu (MDM 2015-0538), the Generalitat Valenciana through PROMETEO/2016/147, and the EPSRC through EP/D503744 and GR/M81830. The authors acknowledge the facilities, and the scientific and technical assistance of the Australian Microscopy & Microanalysis Research Facility at the Centre for Microscopy, Characterisation & Analysis, The University of Western Australia, a facility funded by the University, State and Commonwealth Governments. G.F.T. acknowledges the Australian Government for the provision of an Australian Government Research Training Program (RTP) scholarship.
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Tipo:
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Artículo
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