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Parts-per-million of ruthenium catalyze the selective chain-walking reaction of terminal alkenes

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Parts-per-million of ruthenium catalyze the selective chain-walking reaction of terminal alkenes

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dc.contributor.author Sanz-Navarro, Sergio es_ES
dc.contributor.author Mon-Conejero, Marta es_ES
dc.contributor.author Doménech-Carbó, Antonio es_ES
dc.contributor.author Greco, Rossella es_ES
dc.contributor.author Sánchez-Quesada, Jorge es_ES
dc.contributor.author Espinós-Ferri, Estela es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.date.accessioned 2023-06-26T18:01:27Z
dc.date.available 2023-06-26T18:01:27Z
dc.date.issued 2022-05-20 es_ES
dc.identifier.issn 2041-1723 es_ES
dc.identifier.uri http://hdl.handle.net/10251/194563
dc.description.abstract [EN] The chain-walking of terminal alkenes (also called migration or isomerization reaction) is currently carried out in industry with unselective and relatively costly processes, to give mixtures of alkenes with significant amounts of oligomerized, branched and reduced by-products. Here, it is shown that part-per-million amounts of a variety of commercially available and in-house made ruthenium compounds, supported or not, transform into an extremely active catalyst for the regioselective migration of terminal alkenes to internal positions, with yields and selectivity up to >99% and without any solvent, ligand, additive or protecting atmosphere required, but only heating at temperatures >150 degrees C. The resulting internal alkene can be prepared in kilogram quantities, ready to be used in nine different organic reactions without any further treatment. The chain-walking of terminal alkenes is an industrially relevant reaction. Here, the authors show that part-per-million amounts of a variety of ruthenium compounds catalyze the reaction in yields and selectivity up to >99%, without any solvent or additive. es_ES
dc.description.sponsorship A.L.-P. thanks the financial support by IFF and MICIIN (PID2020-115100GB-I00). We also thank the funding for open access charge to the Universitat Politecnica de Valencia. S.S.-N. thanks a fellowship from MINECO (project number CTQ 2017-86735-P). M.-Mon thanks MICIIN from a contract under the Juan de la Cierva program (FJC2019-040523-I). R.G. thanks a contract from the ITQ (SEV-2016-0683). We thank Dr. I. Dominguez for performing Orbitrap experiments. We thank V. Carbonell Vanaclocha for his help in the laboratory. es_ES
dc.language Inglés es_ES
dc.publisher Nature Publishing Group es_ES
dc.relation.ispartof Nature Communications es_ES
dc.rights Reconocimiento (by) es_ES
dc.title Parts-per-million of ruthenium catalyze the selective chain-walking reaction of terminal alkenes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1038/s41467-022-30320-9 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-86735-P/ES/CATALISIS CON ATOMOS METALICOS AISLADOS Y CLUSTERES ULTRAPEQUEÑOS BIEN DEFINIDOS, SIN LIGANDOS Y CONFINADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MCIU//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115100GB-I00/ES/CLUSTERES CATALITICOS MULTIMETALICOS Y DE ALTA ENTROPIA PARA SINTESIS ORGANICA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//FJC2019-040523-I/ es_ES
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Sanz-Navarro, S.; Mon-Conejero, M.; Doménech-Carbó, A.; Greco, R.; Sánchez-Quesada, J.; Espinós-Ferri, E.; Leyva Perez, A. (2022). Parts-per-million of ruthenium catalyze the selective chain-walking reaction of terminal alkenes. Nature Communications. 13(1):1-9. https://doi.org/10.1038/s41467-022-30320-9 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1038/s41467-022-30320-9 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 13 es_ES
dc.description.issue 1 es_ES
dc.identifier.pmid 35595741 es_ES
dc.identifier.pmcid PMC9123009 es_ES
dc.relation.pasarela S\477628 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades es_ES
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