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Degradation of Plasticised Poly(lactide) Composites with Nanofibrillated Cellulose in Different Hydrothermal Environments

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Degradation of Plasticised Poly(lactide) Composites with Nanofibrillated Cellulose in Different Hydrothermal Environments

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dc.contributor.author Wolf, Mark Henning es_ES
dc.contributor.author Gil-Castell, Óscar es_ES
dc.contributor.author Cea, J. es_ES
dc.contributor.author Carrasco, J. C. es_ES
dc.contributor.author Ribes-Greus, María Desamparados es_ES
dc.date.accessioned 2023-11-10T19:04:55Z
dc.date.available 2023-11-10T19:04:55Z
dc.date.issued 2022 es_ES
dc.identifier.issn 1566-2543 es_ES
dc.identifier.uri http://hdl.handle.net/10251/199516
dc.description.abstract [EN] In this study, bionanocomposite films based on poly(lactide) (PLA) plasticised with poly(ethylene glycol) (PEG) (7.5 wt%) and reinforced with various contents of nanofibrillated cellulose (NFC) (1, 3, 5 wt%) were prepared. The hydrothermal degradation was investigated through immersion in several aqueous environments at temperatures of 8, 23, 58, and 70 °C as a function of time (7, 15, 30, 60, 90 days). The effect of water immersion on the physicochemical properties of the materials was assessed by monitoring the changes in the morphology, thermo-oxidative stability, thermal properties, and molar mass through field emission scanning electron microscopy (FE-SEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and gel permeation chromatography (GPC). The hydrothermal degradation behaviour was not critically affected regardless of the nanofibrillated cellulose content. All the materials revealed certain integrity towards water immersion and hydrolysis effects at low temperatures (8 and 23 °C). The low hydrothermal degradation may be an advantage for using these PLA biocomposites in contact with water at ambient temperatures and limited exposure times. On the other hand, immersion in water at higher temperatures above the glass transition (58 and 70 °C), leads to a drastic deterioration of the properties of these PLA-based materials, in particular to the reduction of the molar mass and the disintegration into small pieces. This hydrothermal degradation behaviour can be considered a feasible option for the waste management of PLA/PEG/NFC bionanocomposites by deposition in hot aqueous environments. es_ES
dc.description.sponsorship This research was funded by Generalitat Valenciana (Conselleria d'Innovacio, Universitats, Ciencia i Societat Digital), as a part of the DEFIANCE research project CIPROM/2021/039 through the PRO-METEO funding program. Generalitat Valenciana is also thanked for the post-doctoral contract of O. Gil-Castell (APOSTD/2020/155). The Innovation Fund for Competitiveness of the Chilean Economic Development Agency (CORFO) is acknowledged for the financial support through the project 13CEI2-21839. Funding for open access charge is recognised to CRUE-Universitat Politecnica de Valencia-thanks to the CRUE-CSIC agreement with Springer Nature. es_ES
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Journal of Polymers and the Environment es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Poly(lactide) (PLA) es_ES
dc.subject Poly(ethylene glycol) (PEG) es_ES
dc.subject Nanofibrillated cellulose (NFC) es_ES
dc.subject Bionanocomposites es_ES
dc.subject Hydrothermal degradation es_ES
dc.subject Water immersion es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Degradation of Plasticised Poly(lactide) Composites with Nanofibrillated Cellulose in Different Hydrothermal Environments es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10924-022-02711-y es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CORPORACION DE FOMENTO DE LA PRODUCCION, CORFO//LEITAT. 13CEI2-21839//CENTRO DE EXCELENCIA EN NANOFIBRAS LEITAT CHILE (CEN LEITAT-CHILE)/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//APOSTD%2F2020%2F155//CONTRATO POSDOCTORAL GVA-GIL CASTELL. PROYECTO: POLIELECTROLITOS FUNCIONALIZADOS PARA PILAS DE COMBUSTIBLE DE METANOL EN SISTEMAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//IDIFEDER%2F2021%2F039//ANALISIS Y OPTIMIZACION MULTI-ESCALA DE LA ARQUITECTURA DE VEHICULOS DE PILA DE COMBUSTIBLE DE HIDROGENO PARA PROMOVER LA DESCARBONIZACION DEL SECTOR TRANSPORTE/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials es_ES
dc.description.bibliographicCitation Wolf, MH.; Gil-Castell, Ó.; Cea, J.; Carrasco, JC.; Ribes-Greus, MD. (2022). Degradation of Plasticised Poly(lactide) Composites with Nanofibrillated Cellulose in Different Hydrothermal Environments. Journal of Polymers and the Environment. 31:2055-2072. https://doi.org/10.1007/s10924-022-02711-y es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1007/s10924-022-02711-y es_ES
dc.description.upvformatpinicio 2055 es_ES
dc.description.upvformatpfin 2072 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 31 es_ES
dc.relation.pasarela S\479488 es_ES
dc.contributor.funder GENERALITAT VALENCIANA es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder CORPORACION DE FOMENTO DE LA PRODUCCION, CORFO es_ES
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dc.subject.ods 08.- Fomentar el crecimiento económico sostenido, inclusivo y sostenible, el empleo pleno y productivo, y el trabajo decente para todos es_ES
dc.subject.ods 09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación es_ES
dc.subject.ods 14.- Conservar y utilizar de forma sostenible los océanos, mares y recursos marinos para lograr el desarrollo sostenible es_ES
dc.subject.ods 15.- Proteger, restaurar y promover la utilización sostenible de los ecosistemas terrestres, gestionar de manera sostenible los bosques, combatir la desertificación y detener y revertir la degradación de la tierra, y frenar la pérdida de diversidad biológica es_ES


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