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A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides

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A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides

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dc.contributor.author Serna Merino, Pedro Manuel es_ES
dc.contributor.author Gates, B. C. es_ES
dc.date.accessioned 2013-04-19T10:55:04Z
dc.date.issued 2011-04-29
dc.identifier.issn 1433-7851
dc.identifier.uri http://hdl.handle.net/10251/28074
dc.description.abstract [EN] No ligands needed: Rhodium complexes supported on HY zeolite catalyze the formation of C[BOND]C bonds by a new mechanism involving cooperation between the metal species and Brønsted acid sites of the zeolite support (see picture). The catalyst operates in the absence of ligands such as halides and shows high selectivity to n-butenes, even in an excess of H2. es_ES
dc.description.sponsorship We acknowledge DOE Basic Energy Sciences for support (Contract No. FG02-04ER15513) and acknowledge beam time and support of the DOE Division of Materials Sciences for its role in the operation and development of beam line MR-CAT at the Advanced Photon Source at Argonne National Laboratory.
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation DOE/FG02-04ER15513 es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Alkene dimerization es_ES
dc.subject Bifunctional catalysis es_ES
dc.subject C[BOND]C bond formation es_ES
dc.subject Rhodium complexes es_ES
dc.subject Zeolites es_ES
dc.title A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/anie.201008086
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Serna Merino, PM.; Gates, BC. (2011). A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides. Angewandte Chemie International Edition. 50(24):5528-5531. doi:10.1002/anie.201008086 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://onlinelibrary.wiley.com/doi/10.1002/anie.201008086/pdf es_ES
dc.description.upvformatpinicio 5528 es_ES
dc.description.upvformatpfin 5531 es_ES
dc.type.version info:eu repo/semantics/publishedVersion es_ES
dc.description.volume 50 es_ES
dc.description.issue 24 es_ES
dc.relation.senia 224131
dc.identifier.pmid 21538737
dc.contributor.funder Department of Energy, EEUU


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