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Experimental and Theoretical Studies on the Radical-Cation-Mediated Imino-Diels_Alder Reaction

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Experimental and Theoretical Studies on the Radical-Cation-Mediated Imino-Diels_Alder Reaction

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dc.contributor.author Pérez Ruiz, Raul es_ES
dc.contributor.author Domingo, Luis R es_ES
dc.contributor.author Jiménez Molero, María Consuelo es_ES
dc.contributor.author Miranda Alonso, Miguel Ángel es_ES
dc.date.accessioned 2013-04-22T13:56:13Z
dc.date.issued 2011
dc.identifier.issn 1523-7060
dc.identifier.uri http://hdl.handle.net/10251/28114
dc.description.abstract [EN] The feasibility of an electron transfer imino-Diels Alder reaction betweenN-benzylideneaniline and arylalkenes in the presence of a pyrylium salt as a photosensitizer has been demonstrated by a combination of product studies, laser flash photolysis (LFP), and DFT theoretical calculations. A stepwise mechanism involving two intermediates and two transition states is proposed. es_ES
dc.description.sponsorship Financial support from the MICINN (Grants CTQ2010-14882, CTQ2009-13699, CTQ2009-11027, and JCI-2010-06204) and from the UPV (Grant No. 20100994 and MCI Program) is gratefully acknowledged. Dedicated to Prof. Dr. Jaime Primo (Universidad Politecnica de Valencia) on the occasion of his 60th birthday. en_EN
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation MICINN/CTQ2010-14882
dc.relation MICINN/CTQ2009-11027
dc.relation MICINN/JCI-2010-06204
dc.relation UPV/20100994
dc.relation.ispartof Organic Letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Photoinduced electron-transfer es_ES
dc.subject Tetrahydroquinoline derivatives es_ES
dc.subject 2,4,6-triphenylpyrylium salt es_ES
dc.subject 4+2 cycloaddition; martinellic acid es_ES
dc.subject Facile synthesis es_ES
dc.subject N-Arylimines es_ES
dc.subject Thiobenzophenone es_ES
dc.subject Mechanisms es_ES
dc.subject Catalysis es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Experimental and Theoretical Studies on the Radical-Cation-Mediated Imino-Diels_Alder Reaction es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/ol201984s
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Pérez Ruiz, R.; Domingo, LR.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2011). Experimental and Theoretical Studies on the Radical-Cation-Mediated Imino-Diels_Alder Reaction. Organic Letters. 13(19):5116-5119. doi:10.1021/ol201984s es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://pubs.acs.org/doi/ipdf/10.1021/ol201984s es_ES
dc.description.upvformatpinicio 5116 es_ES
dc.description.upvformatpfin 5119 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 13 es_ES
dc.description.issue 19 es_ES
dc.relation.senia 202179
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Universitat Politècnica de València


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