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Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene

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Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene

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dc.contributor.author Alonso Ruiz, Rafael es_ES
dc.contributor.author Jiménez Molero, María Consuelo es_ES
dc.contributor.author Miranda Alonso, Miguel Ángel es_ES
dc.date.accessioned 2013-04-22T14:16:31Z
dc.date.issued 2011
dc.identifier.issn 1523-7060
dc.identifier.uri http://hdl.handle.net/10251/28116
dc.description.abstract [EN] Encapsulation within transport proteins strongly reduces the photooxidation rate of (S)- and (R)-2-(9-anthracenyl)propanoic acid (1) and results in a significant stereodifferentiation. The most remarkable effects are observed within human serum albumin (HSA). es_ES
dc.description.sponsorship Financial support from the MICINN (Grant CTQ2010-14882), the Generalitat Valenciana (Prometeo Program, ref 2008/090), and the Carlos III Institute of Health (Red RETICS) is gratefully acknowledged. We also thank Dr. A. Llamas-Saiz and Servicio de Raios X from Universidad de Santiago for his advice and skillfull technical assistance. Dedicated to the memory of Prof. Rafael Suau. en_EN
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Organic Letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Human-serum-albumin es_ES
dc.subject Transient absorption-spectroscopy es_ES
dc.subject Human alpha(1)-acid glycoprotein es_ES
dc.subject Anti-markovnikov photoaddition es_ES
dc.subject Triplet excited-state es_ES
dc.subject Enantiodifferentiating photocyclodimerization es_ES
dc.subject Supramolecular photochirogenesis es_ES
dc.subject 9-substituted anthracenes es_ES
dc.subject Asymmetric photochemistry es_ES
dc.subject Gamma-cyclodextrins es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/ol201209h
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2010-14882/ES/DIADAS FOTOACTIVAS COMO SONDAS PARA LA GENERACION DE ESPECIES TRANSITORIAS EN SISTEMAS MICROHETEROGENEOS DE TIPO BIOMIMETICO/
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO08%2F2008%2F090/ES/Especies fotoactivas como sondas para proteínas/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Alonso Ruiz, R.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2011). Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene. Organic Letters. 13(15):3860-3863. https://doi.org/10.1021/ol201209h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://pubs.acs.org/doi/ipdf/10.1021/ol201209h es_ES
dc.description.upvformatpinicio 3860 es_ES
dc.description.upvformatpfin 3863 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 13 es_ES
dc.description.issue 15 es_ES
dc.relation.senia 193959
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Generalitat Valenciana
dc.contributor.funder Instituto de Salud Carlos III


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