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dc.contributor.author | Alonso Ruiz, Rafael | es_ES |
dc.contributor.author | Jiménez Molero, María Consuelo | es_ES |
dc.contributor.author | Miranda Alonso, Miguel Ángel | es_ES |
dc.date.accessioned | 2013-04-22T14:16:31Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | http://hdl.handle.net/10251/28116 | |
dc.description.abstract | [EN] Encapsulation within transport proteins strongly reduces the photooxidation rate of (S)- and (R)-2-(9-anthracenyl)propanoic acid (1) and results in a significant stereodifferentiation. The most remarkable effects are observed within human serum albumin (HSA). | es_ES |
dc.description.sponsorship | Financial support from the MICINN (Grant CTQ2010-14882), the Generalitat Valenciana (Prometeo Program, ref 2008/090), and the Carlos III Institute of Health (Red RETICS) is gratefully acknowledged. We also thank Dr. A. Llamas-Saiz and Servicio de Raios X from Universidad de Santiago for his advice and skillfull technical assistance. Dedicated to the memory of Prof. Rafael Suau. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | Organic Letters | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Human-serum-albumin | es_ES |
dc.subject | Transient absorption-spectroscopy | es_ES |
dc.subject | Human alpha(1)-acid glycoprotein | es_ES |
dc.subject | Anti-markovnikov photoaddition | es_ES |
dc.subject | Triplet excited-state | es_ES |
dc.subject | Enantiodifferentiating photocyclodimerization | es_ES |
dc.subject | Supramolecular photochirogenesis | es_ES |
dc.subject | 9-substituted anthracenes | es_ES |
dc.subject | Asymmetric photochemistry | es_ES |
dc.subject | Gamma-cyclodextrins | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1021/ol201209h | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CTQ2010-14882/ES/DIADAS FOTOACTIVAS COMO SONDAS PARA LA GENERACION DE ESPECIES TRANSITORIAS EN SISTEMAS MICROHETEROGENEOS DE TIPO BIOMIMETICO/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO08%2F2008%2F090/ES/Especies fotoactivas como sondas para proteínas/ | |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Alonso Ruiz, R.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2011). Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene. Organic Letters. 13(15):3860-3863. https://doi.org/10.1021/ol201209h | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://pubs.acs.org/doi/ipdf/10.1021/ol201209h | es_ES |
dc.description.upvformatpinicio | 3860 | es_ES |
dc.description.upvformatpfin | 3863 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 13 | es_ES |
dc.description.issue | 15 | es_ES |
dc.relation.senia | 193959 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | |
dc.contributor.funder | Generalitat Valenciana | |
dc.contributor.funder | Instituto de Salud Carlos III |