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Sensitive and selective chromogenic sensing of carbon monoxide via reversible axial CO coordination in binuclear rhodium complexes

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Sensitive and selective chromogenic sensing of carbon monoxide via reversible axial CO coordination in binuclear rhodium complexes

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Moragues Pons, ME.; Esteban Moreno, J.; Ros-Lis, JV.; Martínez Mañez, R.; Marcos Martínez, MD.; Martínez, M.; Soto Camino, J.... (2011). Sensitive and selective chromogenic sensing of carbon monoxide via reversible axial CO coordination in binuclear rhodium complexes. Journal of the American Chemical Society. 133:15762-15772. doi:10.1021/ja206251r

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Título: Sensitive and selective chromogenic sensing of carbon monoxide via reversible axial CO coordination in binuclear rhodium complexes
Autor:
Entidad UPV: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic
Fecha difusión:
Resumen:
The study of probes for CO sensing of a family of binuclear rhodium(II) compounds of general formula [Rh 2{(XC 6H 3)P(XC 6H 4)} n(O 2CR) 4-n]·L 2 containing one or two metalated phosphines (in a head-to-tail arrangement) ...[+]
Palabras clave: Air samples , Axial coordination , Axial ligand , Axial positions , Chloroform solutions , CO detection , CO molecule , CO sensing , Color changes , Gasphase , Low detection limit , Rhodium complexes , Silica supports , Thermogravimetric measurement , Two-color , X-ray diffraction techniques , Air quality , Carbon dioxide , Carbon monoxide , Chromium compounds , Color , Colorimetry , Crystal structure , Ligands , Phosphorus compounds , Probes , Rhodium , Silica , X ray diffraction , Rhodium compounds , Binuclear rhodium complex , Chloroform , Phosphine , Rhodium complex , Silicon dioxide , Unclassified drug , Article , Carbon monoxide sensing , Chemical binding , Chemical procedures , Kinetics , Limit of detection , Thermogravimetry , Air , Chemistry Techniques, Analytical , Drug Design , Organometallic Compounds
Derechos de uso: Cerrado
Fuente:
Journal of the American Chemical Society. (issn: 0002-7863 )
DOI: 10.1021/ja206251r
Editorial:
American Chemical Society
Versión del editor: http://dx.doi.org/10.1021/ja206251r
Agradecimientos:
The authors wish to express their gratitude to the Spanish Ministerio de Ciencia y e Innovacion (projects MAT2009-14564-C04-01 and CTQ2009-14443-C02-02) and Generalitat Valenciana (project PROMETEO/2009/016) for their ...[+]
Tipo: Artículo

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