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Conversion of Methane into C1 Oxygenates by Deep-UV Photolysis on SolidSurfaces: Influence of the Nature of the Solid and Optimization of PhotolysisConditions

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Conversion of Methane into C1 Oxygenates by Deep-UV Photolysis on SolidSurfaces: Influence of the Nature of the Solid and Optimization of PhotolysisConditions

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Sastre Calabuig, F.; Fornes Seguí, V.; Corma Canós, A.; García Gómez, H. (2012). Conversion of Methane into C1 Oxygenates by Deep-UV Photolysis on SolidSurfaces: Influence of the Nature of the Solid and Optimization of PhotolysisConditions. Chemistry - A European Journal. 18(6):1820-1825. doi:10.1002/chem.201102273

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/29580

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Título: Conversion of Methane into C1 Oxygenates by Deep-UV Photolysis on SolidSurfaces: Influence of the Nature of the Solid and Optimization of PhotolysisConditions
Autor:
Entidad UPV: Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
Deep-UV photolysis (either 165 or 185 nm) of surface hydroxy groups leads to homolytic O H bondcleavage with the generation of oxyl radicals that can initiate the room-temperature radical-chain methane activation. Whilst ...[+]
Palabras clave: Methane , Oxygenates , Photolysis , Solid-state reactions , Surface chemistry
Derechos de uso: Cerrado
Fuente:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201102273
Editorial:
Wiley-VCH Verlag
Versión del editor: dx.doi.org/10.1002/chem.201102273
Agradecimientos:
Financial support by the Spanish MICINN (Consolider Ingenio MULTI-CAT and CTQ2009-11586) is gratefully acknowledged.
Tipo: Artículo

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