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Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions

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Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions

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dc.contributor.author Merino Marcos, Estibaliz es_ES
dc.contributor.author Poli, Evelyne es_ES
dc.contributor.author Díaz Morales, Urbano Manuel es_ES
dc.contributor.author Brunel, Daniel es_ES
dc.date.accessioned 2013-09-02T13:44:52Z
dc.date.issued 2012
dc.identifier.issn 1477-9226
dc.identifier.uri http://hdl.handle.net/10251/31696
dc.description.abstract [EN] This manuscript describes the synthesis and structural study of new second generation Hoveyda¿Grubbs catalysts: 1,3-dimesitylacenaphthylenyl- 4,5-imidazolin-2-ylidene (BIAN-NHC) ruthenium isopropoxybenzylidene dichloride 3 and 1,3-bis- (2,6-dimethylphenyl)-2,3-dihydro-1H-imidazole Cl2Ru(vCHo- O-i-PrC6H4) 4. The electrochemical and catalytic behavior of these new complexes was compared with the conventional NHC carbene Hoveyda II IMes-type complexes 1 and 2 for ring closing metathesis reactions. es_ES
dc.description.sponsorship We thank Dr Berta Gomez-Lor for allowing us to use the cyclic voltammetry instrumentation, Dr J. A. Vidal-Moya for his support in the kinetic experiments and Dr Marcelo Domine for the HRMS measurements. We thank Avelino Corma, Felix Sanchez and Marta Iglesias for helpful discussions. E. M. also thanks Ministerio de Ciencia e Innovacion for a contract of the "Juan de la Cierva" program. Financial support by Consolider-Ingenio 2010 (MULTICAT project) and MAT2011-29020-C02-01 is additionally acknowledged.
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof DALTON TRANSACTIONS es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Face donor properties es_ES
dc.subject Olefin metathesis es_ES
dc.subject Imidazolin-2-Ylidene ligands es_ES
dc.subject Imidazol-2-Ylidene ligands es_ES
dc.subject Cross-metathesis es_ES
dc.subject Catalysts es_ES
dc.subject Metal es_ES
dc.subject Efficient es_ES
dc.subject Bearing es_ES
dc.subject Rcm es_ES
dc.title Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1039/c2dt31540h
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-01/ES/CATALIZADORES HIBRIDOS MULTIFUNCIONALES BASADOS EN UNIDADES ESTRUCTURALES ORGANICAS-INORGANICAS UTILIZADOS EN REACCIONES CASCADA/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Merino Marcos, E.; Poli, E.; Díaz Morales, UM.; Brunel, D. (2012). Synthesis and characterization of new ruthenium N-heterocyclic carbene Hoveyda II-type complexes. Study of reactivity in ring closing metathesis reactions. DALTON TRANSACTIONS. 41(36):10913-10918. https://doi.org/10.1039/c2dt31540h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c2dt31540h es_ES
dc.description.upvformatpinicio 10913 es_ES
dc.description.upvformatpfin 10918 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 41 es_ES
dc.description.issue 36 es_ES
dc.relation.senia 236233
dc.identifier.eissn 1477-9234
dc.identifier.pmid 22878532
dc.contributor.funder Ministerio de Ciencia e Innovación


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