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dc.contributor.author | Poli, Evelyne | es_ES |
dc.contributor.author | Merino Marcos, Estibaliz | es_ES |
dc.contributor.author | Díaz Morales, Urbano Manuel | es_ES |
dc.contributor.author | Brunel, Daniel | es_ES |
dc.contributor.author | Corma Canós, Avelino | |
dc.date.accessioned | 2013-09-04T09:20:40Z | |
dc.date.available | 2013-09-04T09:20:40Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 0959-9428 | |
dc.identifier.uri | http://hdl.handle.net/10251/31747 | |
dc.description.abstract | The porous organosilica framework containing Troger's base (TB) prepared by mild sol-gel synthesis from 2,8-bis-silylated TB precursor contains a mixture of two point attached TB and one point attached TB units, resulting from unexpected partial Si-C bond cleavage as demonstrated by (29)Si MAS NMR spectroscopy and by selective chemo-desorption of the anchored organic part of the hybrid material. | es_ES |
dc.description.sponsorship | We are thankful for financial support by Consolider-Ingenio 2010 (MULTICAT project). E.M. thanks Ministerio de Ciencia y Innovacion by the support through Juan de la Cierva contract. The authors are indebted to Dr Alejandro Vidal-Moya for technical assistance and fruitful discussion on <SUP>13</SUP>C and <SUP>29</SUP>Si MAS NMR spectroscopies. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Journal of Materials Chemistry | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | PERIODIC MESOPOROUS ORGANOSILICAS | es_ES |
dc.subject | HYBRID MATERIALS | es_ES |
dc.subject | NUCLEOPHILIC DISPLACEMENT | es_ES |
dc.subject | MECHANISTIC IMPLICATIONS | es_ES |
dc.subject | CATALYTIC-ACTIVITY | es_ES |
dc.subject | SELF-ORGANIZATION | es_ES |
dc.subject | ORGANIC GROUPS | es_ES |
dc.subject | CHANNEL WALLS | es_ES |
dc.subject | SILICA-GEL | es_ES |
dc.subject | CRYSTAL | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Si-C attachment points during sol-gel synthesis of organosilicas from 2,8 bis-silylated Troeger s base as building block precursor | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/c1jm10426h | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Poli, E.; Merino Marcos, E.; Díaz Morales, UM.; Brunel, D.; Corma Canós, A. (2011). Si-C attachment points during sol-gel synthesis of organosilicas from 2,8 bis-silylated Troeger s base as building block precursor. Journal of Materials Chemistry. 21(24):8524-8527. doi:10.1039/c1jm10426h | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c1jm10426h | es_ES |
dc.description.upvformatpinicio | 8524 | es_ES |
dc.description.upvformatpfin | 8527 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 21 | es_ES |
dc.description.issue | 24 | es_ES |
dc.relation.senia | 209022 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |