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Enhanced photochemical [6pi] electrocyclization within the lipophilic protein binding site

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Enhanced photochemical [6pi] electrocyclization within the lipophilic protein binding site

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Nombre: org. lett. 14.pdf
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dc.contributor.author Marín Melchor, Mireia es_ES
dc.contributor.author Lhiaubet, Virginie Lyria es_ES
dc.contributor.author Miranda Alonso, Miguel Ángel es_ES
dc.date.accessioned 2013-10-22T15:00:57Z
dc.date.issued 2012
dc.identifier.issn 1523-7060
dc.identifier.uri http://hdl.handle.net/10251/33011
dc.description.abstract Photocyclization of N-methyldiphenylamine to N-methylcarbazole is achieved within the microenvironment provided by site I of serum albumins. Quantum yield determinations, combined with transient absorption spectroscopic detection of the dihydrocarbazole intermediate, demonstrate that protein encapsulation provides a subtle control of the kinetic parameters, leading to optimized efficiencies. es_ES
dc.description.sponsorship This work was funded by the Spanish Government (Project CTQ2009-13699, Ramon y Cajal contract RyC-2007-00476 to V.L.-V. and JAE-predoc contract to M.M.) and the Generalitat Valenciana (Prometeo/2008/090). en_EN
dc.format.extent 4 es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Organic letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Human-serum-albumin es_ES
dc.subject N methyldiphenylamine es_ES
dc.subject Drug es_ES
dc.subject Photoconversion es_ES
dc.subject State es_ES
dc.subject Stereodifferentiation es_ES
dc.subject Photocyclization es_ES
dc.subject Methylcarbazole es_ES
dc.subject Diphenylamines es_ES
dc.subject Switches es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Enhanced photochemical [6pi] electrocyclization within the lipophilic protein binding site es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/ol3003805
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2009-13699/ES/CTQ2009-13699/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO08%2F2008%2F090/ES/Especies fotoactivas como sondas para proteínas/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MEC//RYC-2007-00476/ES/RYC-2007-00476/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Marín Melchor, M.; Lhiaubet, VL.; Miranda Alonso, MÁ. (2012). Enhanced photochemical [6pi] electrocyclization within the lipophilic protein binding site. Organic letters. 14(7):1788-1791. https://doi.org/10.1021/ol3003805 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://pubs.acs.org/doi/pdf/10.1021/ol3003805 es_ES
dc.description.upvformatpinicio 1788 es_ES
dc.description.upvformatpfin 1791 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 14 es_ES
dc.description.issue 7 es_ES
dc.relation.senia 222990
dc.contributor.funder Generalitat Valenciana es_ES


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