Sans, V.; Karbass, N.; Burguete, MI.; Compañ Moreno, V.; García-Verdugo, E.; Luis, SV.; Pawlak, M. (2011). Polymer-Supported Ionic-Liquid-Like Phases (SILLPs): Transferring Ionic Liquid Properties to Polymeric Matrices. Chemistry - A European Journal. 17:1894-1906. doi:10.1002/chem.201001873
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/33282
Title:
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Polymer-Supported Ionic-Liquid-Like Phases (SILLPs): Transferring Ionic Liquid Properties to Polymeric Matrices
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Author:
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Sans, Victor
Karbass, Naima
Burguete, M. Isabel
Compañ Moreno, Vicente
García-Verdugo, Eduardo
Luis, Santiago V.
Pawlak, Milena
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UPV Unit:
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Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada
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Issued date:
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Abstract:
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Abstract: The physico-chemical properties
of polymers with ionic-liquid-like
moieties covalently bound to their surfaces
(SILLPs) have been studied by
thermal and spectroscopic techniques,
as well as by direct impedance ...[+]
Abstract: The physico-chemical properties
of polymers with ionic-liquid-like
moieties covalently bound to their surfaces
(SILLPs) have been studied by
thermal and spectroscopic techniques,
as well as by direct impedance and dielectric
measurements, and compared to
those of the corresponding bulk ionic
liquids. The effective transfer of properties
from ionic liquids in solution to
the supported species has thereby been
demonstrated. The effects of the chemical
nature of these tunable ¿solid solvents¿
on their macroscopic swelling
and microwave heating, as well as the
stabilities and activities of different catalytic
moieties immobilized on the
SILLPs, have been studied. Finally, the
experimental effect observed in microwave
heating can be directly correlated
with the values of tand derived from
dielectric measurements.
[-]
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Subjects:
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Catalysis
,
Ionic liquids
,
Polarity
,
Solvatochromism
,
Supported catalysts
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Copyrigths:
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Cerrado |
Source:
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Chemistry - A European Journal. (issn:
0947-6539
)
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DOI:
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10.1002/chem.201001873
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Publisher:
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Wiley-VCH Verlag
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Publisher version:
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http://dx.doi.org/10.1002/chem.201001873
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Project ID:
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MICINN/CTQ2008-04412/BQU
...[+]
MICINN/CTQ2008-04412/BQU
CSIC/2009-801092
GV-FEDER/ACOMP/2010/280
IMPIVA/IMIDIC/2009/155
Bancaixa-UJI/P1 2009-58
Consejo Superior de Investigaciones Científicas
Generalitat Valenciana
[-]
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Thanks:
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We thank the Spanish MICINN and Feder Funds (CTQ2008-04412/BQU) and the CSIC (2009-801092), GV, and Feder Funds (ACOMP/2010/280 and IMPIVA IMIDIC/2009/155), and Bancaixa-UJI (P1 2009-58) for financial support.
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Type:
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Artículo
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