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A Molecular Probe for the Highly Selective Chromogenic Detection of DFP, a Mimic of Sarin and Soman Nerve Agents

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A Molecular Probe for the Highly Selective Chromogenic Detection of DFP, a Mimic of Sarin and Soman Nerve Agents

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dc.contributor.author Gotor Candel, Raul Jesús es_ES
dc.contributor.author Costero Nieto, Ana María es_ES
dc.contributor.author Gil Grau, Salvador es_ES
dc.contributor.author Parra Álvarez, Margarita es_ES
dc.contributor.author Martínez Mañez, Ramón es_ES
dc.contributor.author Sancenón Galarza, Félix
dc.date.accessioned 2013-11-11T11:27:55Z
dc.date.issued 2011-10-17
dc.identifier.issn 0947-6539
dc.identifier.uri http://hdl.handle.net/10251/33411
dc.description.abstract Lethal-weapon visualization: A novel triarylmethanol derivative, which is able to colorimetrically distinguish diisopropylfluorophosphate (DFP; a mimic of Sarin and Soman) from other nerve-agent simulants, is reported (see picture). This probe was designed to contain two reactive sites: an OH group that provides a suitable reactive group for nerve agents and a tert-butyldimethylsilylether moiety that is able to react with fluoride, which is a specific byproduct of the phosphorylation of OH by DFP. es_ES
dc.description.sponsorship We thank the Spanish Government (project MAT2009-14564-C04) and the Regional Valencian Government (Generalitat Valencia; project PROMETEO/2009/016 and ACOMP07/080) for support. S.R. is grateful to the Generalitat Valenciana for the fellowship awarded. SCSIE (Universidad de Valencia) is gratefully acknowledged for all the equipment employed. en_EN
dc.format.extent 4 es_ES
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Chemosensors es_ES
dc.subject Chromogenic detection es_ES
dc.subject DFP recognition es_ES
dc.subject Nerve-agent simulants es_ES
dc.subject Organophosphonates es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title A Molecular Probe for the Highly Selective Chromogenic Detection of DFP, a Mimic of Sarin and Soman Nerve Agents es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/chem.201102241
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2009-14564-C04/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Generalitat Valenciana//PROMETEO09%2F2009%2F016/ES/Ayuda prometeo 2009 para el grupo de diseño y desarrollo de sensores/ / es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Generalitat Valenciana//ACOMP07%2F2009%2F080/ES/Desarrollo de quimiosensores en solución para especies de pequeño tamaño con interés biológico/ / es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Gotor Candel, RJ.; Costero Nieto, AM.; Gil Grau, S.; Parra Álvarez, M.; Martínez Mañez, R.; Sancenón Galarza, F. (2011). A Molecular Probe for the Highly Selective Chromogenic Detection of DFP, a Mimic of Sarin and Soman Nerve Agents. Chemistry - A European Journal. 17:11994-11997. https://doi.org/10.1002/chem.201102241 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/chem.201102241 es_ES
dc.description.upvformatpinicio 11994 es_ES
dc.description.upvformatpfin 11997 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 17 es_ES
dc.relation.senia 206716
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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