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[Fe(TPT)2/3{MI(CN)2}2]·nSolv (MI=Ag, Au): new bimetallic porous coordination polymers with spin-crossover properties

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[Fe(TPT)2/3{MI(CN)2}2]·nSolv (MI=Ag, Au): new bimetallic porous coordination polymers with spin-crossover properties

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Arcis-Castillo, Z.; Muñoz Roca, MDC.; Molnár, G.; Bousseksou, A.; Real, JA. (2013). [Fe(TPT)2/3{MI(CN)2}2]·nSolv (MI=Ag, Au): new bimetallic porous coordination polymers with spin-crossover properties. Chemistry - A European Journal. 19(21):6851-6861. https://doi.org/10.1002/chem.201203559

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Title: [Fe(TPT)2/3{MI(CN)2}2]·nSolv (MI=Ag, Au): new bimetallic porous coordination polymers with spin-crossover properties
Author: Arcis-Castillo, Zulema Muñoz Roca, María del Carmen Molnár, Gábor Bousseksou, Azzedine Real, José Antonio
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
Two new heterobimetallic porous coordination polymers with the formula [Fe(TPT)2/3{MI(CN)2}2]¿nSolv (TPT=[(2,4,6-tris(4-pyridyl)-1,3,5-triazine]; MI=Ag (nSolv=0, 1¿MeOH, 2¿CH2Cl2), Au (nSolv=0, 2¿CH2Cl2)) have been synthesized ...[+]
Subjects: Coordination polymers , Iron , Porosity , Self-assembly , Spin crossover
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201203559
Publisher:
Wiley-VCH Verlag
Publisher version: http://onlinelibrary.wiley.com/doi/10.1002/chem.201203559/suppinfo
Project ID:
info:eu-repo/grantAgreement/MICINN//CTQ2010-18414/ES/MATERIALES MULTIPROPIEDAD BASADOS EN EL FENOMENO "SPIN CROSSOVER": MEMORIAS Y SENSORES MOLECULARES/
info:eu-repo/grantAgreement/GVA//ACOMP%2F2012%2F233/
info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F049/
Thanks:
This work was supported by the Spanish Ministerio de Ciencia e Innovacion (MICINN, presently the Ministerio de Economia y Competitividad) and FEDER funds (CTQ2010-18414), the Generalitat Valenciana through projects ...[+]
Type: Artículo

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Galet, A., Niel, V., Muñoz, M. C., & Real, J. A. (2003). Synergy between Spin Crossover and Metallophilicity in Triple Interpenetrated 3D Nets with the NbO Structure Type. Journal of the American Chemical Society, 125(47), 14224-14225. doi:10.1021/ja0377347

Galet, A., Muñoz, M. C., Martínez, V., & Real, J. A. (2004). Supramolecular isomerism in spin crossover networks with aurophilic interactions. Chem. Commun., (20), 2268-2269. doi:10.1039/b409974e

Niel, V., Thompson, A. L., Muñoz, M. C., Galet, A., Goeta, A. E., & Real, J. A. (2003). Crystalline-State Reaction with Allosteric Effect in Spin-Crossover, Interpenetrated Networks with Magnetic and Optical Bistability. Angewandte Chemie, 115(32), 3890-3893. doi:10.1002/ange.200351853

Niel, V., Thompson, A. L., Muñoz, M. C., Galet, A., Goeta, A. E., & Real, J. A. (2003). Crystalline-State Reaction with Allosteric Effect in Spin-Crossover, Interpenetrated Networks with Magnetic and Optical Bistability. Angewandte Chemie International Edition, 42(32), 3760-3763. doi:10.1002/anie.200351853

Agustí, G., Cobo, S., Gaspar, A. B., Molnár, G., Moussa, N. O., Szilágyi, P. Á., … Bousseksou, A. (2008). Thermal and Light-Induced Spin Crossover Phenomena in New 3D Hofmann-Like Microporous Metalorganic Frameworks Produced As Bulk Materials and Nanopatterned Thin Films. Chemistry of Materials, 20(21), 6721-6732. doi:10.1021/cm8019878

Muñoz-Lara, F. J., Gaspar, A. B., Muñoz, M. C., Arai, M., Kitagawa, S., Ohba, M., & Real, J. A. (2012). Sequestering Aromatic Molecules with a Spin-Crossover FeII Microporous Coordination Polymer. Chemistry - A European Journal, 18(26), 8013-8018. doi:10.1002/chem.201200377

Bartual-Murgui, C., Ortega-Villar, N. A., Shepherd, H. J., Muñoz, M. C., Salmon, L., Molnár, G., … Real, J. A. (2011). Enhanced porosity in a new 3D Hofmann-like network exhibiting humidity sensitive cooperative spin transitions at room temperature. Journal of Materials Chemistry, 21(20), 7217. doi:10.1039/c0jm04387g

Bartual-Murgui, C., Salmon, L., Akou, A., Ortega-Villar, N. A., Shepherd, H. J., Muñoz, M. C., … Bousseksou, A. (2011). Synergetic Effect of Host-Guest Chemistry and Spin Crossover in 3D Hofmann-like Metal-Organic Frameworks [Fe(bpac)M(CN)4] (M=Pt, Pd, Ni). Chemistry - A European Journal, 18(2), 507-516. doi:10.1002/chem.201102357

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