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Azo dyes functionalized with alkoxysilyl ethers as chemodosimeters for the chromogenic detection of the fluoride anion

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Azo dyes functionalized with alkoxysilyl ethers as chemodosimeters for the chromogenic detection of the fluoride anion

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dc.contributor.author Agostini, Alessandro es_ES
dc.contributor.author Milani, Michele es_ES
dc.contributor.author Martínez Mañez, Ramón es_ES
dc.contributor.author Licchelli, Maurizio es_ES
dc.contributor.author Soto Camino, Juan es_ES
dc.contributor.author Sancenón Galarza, Félix es_ES
dc.date.accessioned 2013-11-28T12:19:35Z
dc.date.issued 2012-09
dc.identifier.issn 1861-4728
dc.identifier.uri http://hdl.handle.net/10251/34128
dc.description.abstract Finding fluoride: An azo dye functionalized with tert-butyldimethylsilyl ether has been synthesized and used as a selective chromogenic fluoride sensor in the acetonitrile/water mixtures. The chromogenic response arises from the fluoride-induced hydrolysis of the silyl ether moiety, which yields a highly colored phenolate anion. The sensor molecule can be grafted to silica to make dip-sticks for fluoride sensing. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. es_ES
dc.description.sponsorship The authors thank the Spanish Government (project MAT2009-14564-C04), the Generalitat Valenciana (project PROMETEO/2009/016) and the CIBER-BBN for their support. A.A. also thanks the Generalitat Valenciana for his Santiago Grisolia fellowship. en_EN
dc.format.extent 5 es_ES
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation Spanish Government [MAT2009-14564-C04] es_ES
dc.relation Generalitat Valenciana [PROMETEO/2009/016] es_ES
dc.relation CIBER-BBN es_ES
dc.relation Generalitat Valenciana es_ES
dc.relation.ispartof Chemistry - An Asian Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Fluorides es_ES
dc.subject Hydrolysis es_ES
dc.subject Sensors es_ES
dc.subject Silyl ether es_ES
dc.subject Chemodosimeters es_ES
dc.subject Fluoride anions es_ES
dc.subject Functionalized es_ES
dc.subject Sensor molecules es_ES
dc.subject Silyl ethers es_ES
dc.subject Tert-butyldimethylsilyl es_ES
dc.subject Azo dyes es_ES
dc.subject Fluorine compounds es_ES
dc.subject Organic compounds es_ES
dc.subject Phenols es_ES
dc.subject Silica es_ES
dc.subject Ethers es_ES
dc.subject Acetonitrile es_ES
dc.subject Acetonitrile derivative es_ES
dc.subject Anion es_ES
dc.subject Azo compound es_ES
dc.subject Coloring agent es_ES
dc.subject Ether derivative es_ES
dc.subject Fluoride es_ES
dc.subject Organosilicon derivative es_ES
dc.subject T butyldimethylsilyl compounds es_ES
dc.subject T-butyldimethylsilyl compounds es_ES
dc.subject Water es_ES
dc.subject Article es_ES
dc.subject Chemistry es_ES
dc.subject Colorimetry es_ES
dc.subject Acetonitriles es_ES
dc.subject Anions es_ES
dc.subject Azo Compounds es_ES
dc.subject Coloring Agents es_ES
dc.subject Organosilicon Compounds es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Azo dyes functionalized with alkoxysilyl ethers as chemodosimeters for the chromogenic detection of the fluoride anion es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/asia.201200323
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Agostini, A.; Milani, M.; Martínez Mañez, R.; Licchelli, M.; Soto Camino, J.; Sancenón Galarza, F. (2012). Azo dyes functionalized with alkoxysilyl ethers as chemodosimeters for the chromogenic detection of the fluoride anion. Chemistry - An Asian Journal. 7:2040-2044. doi:10.1002/asia.201200323 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/asia.201200323 es_ES
dc.description.upvformatpinicio 2040 es_ES
dc.description.upvformatpfin 2044 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 7 es_ES
dc.relation.senia 230306


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