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Water-stabilized three-and four-atom palladium clusters as highly active catalytic species in ligand-free C-C cross coupling reactions

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Water-stabilized three-and four-atom palladium clusters as highly active catalytic species in ligand-free C-C cross coupling reactions

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dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Oliver Meseguer, Judit es_ES
dc.contributor.author Rubio Marqués, Paula es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2014-05-22T12:54:03Z
dc.date.issued 2013-10-25
dc.identifier.issn 1433-7851
dc.identifier.uri http://hdl.handle.net/10251/37686
dc.description.abstract Auf kleinstem Nenner: Palladiumcluster mit drei oder vier Atomen erwiesen sich als katalytisch aktive Spezies in ligandenfreien palladiumkatalysierten C-C-Kupplungen (siehe Bild). Die Cluster konnten in Wasser stabilisiert und ohne Aktivitätseinbuße lange Zeit aufbewahrt werden. Hohe Produktausbeuten und Umsatzfrequenzen (TOF) bis 105¿h¿1 wurden beobachtet. es_ES
dc.description.sponsorship Financial support by Consolider-Ingenio 2010 (proyecto MULTICAT) and the "Severo Ochoa" program is acknowledged. A. L.-P. and J.O.-M. thank the ITQ for a contract. P. R.-M. thanks the MEC for an FPU contract. The MALDI-TOF analysis was carried out in The SCSIE_University of Valencia Proteomics Unit, a member of the ISCIII ProteoRed Proteomics Platform. en_EN
dc.format.extent 6 es_ES
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation Consolider-Ingenio 2010 (proyecto MULTICAT) es_ES
dc.relation Severo Ochoa program es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Cluster es_ES
dc.subject Homogene Katalyse es_ES
dc.subject Kreuzkupplungen es_ES
dc.subject Ligandenfreie Bedingungen es_ES
dc.subject Palladium es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Water-stabilized three-and four-atom palladium clusters as highly active catalytic species in ligand-free C-C cross coupling reactions es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/anie.201303188
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Leyva Perez, A.; Oliver Meseguer, J.; Rubio Marqués, P.; Corma Canós, A. (2013). Water-stabilized three-and four-atom palladium clusters as highly active catalytic species in ligand-free C-C cross coupling reactions. Angewandte Chemie International Edition. 125(44):11768-11773. doi:10.1002/anie.201303188 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://onlinelibrary.wiley.com/doi/10.1002/ange.201303188/abstract es_ES
dc.description.upvformatpinicio 11768 es_ES
dc.description.upvformatpfin 11773 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 125 es_ES
dc.description.issue 44 es_ES
dc.relation.senia 258365
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