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Very Small (3-6 Atoms) Gold Cluster Catalyzed Carbón-Carbon and Carbon-Heteroatom Bond-Forming Reactions in Solution

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Very Small (3-6 Atoms) Gold Cluster Catalyzed Carbón-Carbon and Carbon-Heteroatom Bond-Forming Reactions in Solution

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dc.contributor.author Oliver Meseguer, Judit es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2014-07-03T08:31:48Z
dc.date.issued 2013-12-01
dc.identifier.issn 1867-3880
dc.identifier.uri http://hdl.handle.net/10251/38546
dc.description.abstract Small gold clusters containing 3-6 atoms (submolar) catalyze different carbon-carbon and carbon-heteroatom bond-forming reactions. They can be formed in situ from gold salts, complexes and nanoparticles under acidic conditions. A sound determination of possible clusters in solution for previously reported reactions can only be assessed after accurate kinetic studies, in situ and ex situ spectroscopic measurements, and comparison with preformed gold clusters, as the stability of gold salts and complexes can vary depending on the type of catalyst and the experimental conditions. The results here reported could be expanded not only to other gold-catalyzed reactions but also to other catalytic metal systems. es_ES
dc.description.sponsorship Financial support by the Severo Ochoa program and Consolider-Ingenio 2010 (proyecto MULTICAT) from Ministerio de Ciencia e Innovacion (MCIINN) is acknowledged. J. O.-M. thanks Instituto de Tecnologia Quimica (ITQ) for a postgraduate scholarship. A. L.-P. thanks Consejo Superior de Investigaciones Cientificas (CSIC) for a contract. en_EN
dc.format.extent 7 es_ES
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Molecular clusters es_ES
dc.subject Gold es_ES
dc.subject Carbon-heteroatom bond formation es_ES
dc.subject Carbon-carbon bond formation es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Very Small (3-6 Atoms) Gold Cluster Catalyzed Carbón-Carbon and Carbon-Heteroatom Bond-Forming Reactions in Solution es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cctc.201300695
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Oliver Meseguer, J.; Leyva Perez, A.; Corma Canós, A. (2013). Very Small (3-6 Atoms) Gold Cluster Catalyzed Carbón-Carbon and Carbon-Heteroatom Bond-Forming Reactions in Solution. ChemCatChem. 5(12):3509-3515. doi:10.1002/cctc.201300695 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/10.1002/cctc.201300695 es_ES
dc.description.upvformatpinicio 3509 es_ES
dc.description.upvformatpfin 3515 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.description.issue 12 es_ES
dc.relation.senia 258651
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Instituto de Tecnología Química UPV-CSIC es_ES
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