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Preparation of Glycerol Carbonate Esters by using Hybrid Nafion-Silica Catalyst

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Preparation of Glycerol Carbonate Esters by using Hybrid Nafion-Silica Catalyst

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dc.contributor.author Climent Olmedo, María José es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Iborra Chornet, Sara es_ES
dc.contributor.author Martínez Silvestre, Sergio es_ES
dc.contributor.author Velty ., Alexandra es_ES
dc.date.accessioned 2014-09-29T10:14:31Z
dc.date.issued 2013-07
dc.identifier.issn 1864-5631
dc.identifier.uri http://hdl.handle.net/10251/40395
dc.description.abstract Glycerol carbonate esters (GCEs), which are valuable biomass-deriv. compds., have been prepd. through the direct esterification of glycerol carbonate and long org. acids with different chain lengths, in the absence of solvent, and with heterogeneous catalysts, including acidic-org. resins, zeolites, and hybrid org.-inorg. acids. The best results, in terms of activity and selectivity towards GCEs, were obtained using a Nafion-silica composite. A full reaction scheme has been established, and it has been demonstrated that an undesired competing reaction results in the generation of glycerol and esters derived from a secondary hydrolysis of the endocyclic ester group, which is attributed to water formed during the esterification reaction. The influence of temp., substrate ratio, catalyst-to-substrate ratio, and the use of solvent has been studied and, under optimized reaction conditions and with the adequate catalyst, it was possible to achieve 95 % selectivity for the desired product at 98 % conversion. It was demonstrated that the reaction rate decreased as the no. of carbon atoms in the linear alkyl chain of the carboxylic acid increased for both p-toluenesulfonic acid and Nafion-silica nanocomposite (Nafion SAC-13) catalysts. After fitting the exptl. data to a mechanistically based kinetic model, the reaction kinetic parameters for Nafion SAC-13 catalysis were detd. and compared for reactions involving different carboxylic acids. A kinetic study showed that the reduced reactivity of carboxylic acids with increasing chain lengths could be explained by inductive as well as steric effects. es_ES
dc.description.sponsorship The authors wish to acknowledge the Spanish Science and Innovation Ministry (Consolider Ingenio 2010, CTQ-2011-27550 and MULTICAT CSD2009-00050 projects) and the Generalitat Valenciana (Prometeo program) for their financial support. S.M. thanks the Ministerio de Educacion for a FPI fellowship. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof ChemSusChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Biomass es_ES
dc.subject Carboxylic acids es_ES
dc.subject Esterification es_ES
dc.subject Heterogeneous catalysts es_ES
dc.subject Solid-state structures es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Preparation of Glycerol Carbonate Esters by using Hybrid Nafion-Silica Catalyst es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cssc.201300146
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2011-27550/ES/TRANSFORMACION CATALITICA DE BIOMASA EN DIESEL Y EN PRODUCTOS QUIMICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Climent Olmedo, MJ.; Corma Canós, A.; Iborra Chornet, S.; Martínez Silvestre, S.; Velty ., A. (2013). Preparation of Glycerol Carbonate Esters by using Hybrid Nafion-Silica Catalyst. ChemSusChem. 6(7):1224-1234. doi:10.1002/cssc.201300146 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cssc.201300146 es_ES
dc.description.upvformatpinicio 1224 es_ES
dc.description.upvformatpfin 1234 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 6 es_ES
dc.description.issue 7 es_ES
dc.relation.senia 246975
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Educación es_ES
dc.contributor.funder Generalitat Valenciana es_ES
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