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Activity of ceria and ceria-supported gold nanoparticles for the carbamoylation of aliphatic amines by dimethyl carbonate

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Activity of ceria and ceria-supported gold nanoparticles for the carbamoylation of aliphatic amines by dimethyl carbonate

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Nombre: Juárez;Corma;García ...
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dc.contributor.author Juárez Marín, Raquel es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2014-12-18T13:36:38Z
dc.date.available 2014-12-18T13:36:38Z
dc.date.issued 2011-09-19
dc.identifier.issn 0033-4545
dc.identifier.uri http://hdl.handle.net/10251/45606
dc.description.abstract Aliphatic amines react sluggishly with dimethyl carbonate (DMC) to give a mixture of N-methylation and carbamoylation. Nanoparticulated ceria as catalyst increases, in general, conversion and selectivity toward carbamoylation. This increase in catalytic activity and selectivity toward carbamoylation is even increased by deposition of Au nanoparticles on ceria. However, in contrast to aromatic amines for which a complete selectivity toward carbamoylation using ceria-supported Au nanoparticles can be achieved, the catalytic carbamoylation of aliphatic amines by ceria-supported Au nanoparticles occurs only with moderate selectivity. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Science and Innovation (Consolider 2010-CSD2009-0050 and CTQ2009-11586) is gratefully acknowledged. R.J. thanks the Spanish Ministry of Education for a postgraduate scholarship. en_EN
dc.language Inglés es_ES
dc.publisher International Union of Pure and Applied Chemistry es_ES
dc.relation.ispartof Pure and Applied Chemistry es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Carbamoylation es_ES
dc.subject Catalysts es_ES
dc.subject Gold es_ES
dc.subject Gold nanoparticles es_ES
dc.subject Green chemistry es_ES
dc.subject Phosgene-free synthesis of isocyanates es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Activity of ceria and ceria-supported gold nanoparticles for the carbamoylation of aliphatic amines by dimethyl carbonate es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1351/PAC-CON-11-06-06
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Juárez Marín, R.; Corma Canós, A.; García Gómez, H. (2011). Activity of ceria and ceria-supported gold nanoparticles for the carbamoylation of aliphatic amines by dimethyl carbonate. Pure and Applied Chemistry. 84(3):685-694. https://doi.org/10.1351/PAC-CON-11-06-06 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1351/PAC-CON-11-06-06 es_ES
dc.description.upvformatpinicio 685 es_ES
dc.description.upvformatpfin 694 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 84 es_ES
dc.description.issue 3 es_ES
dc.relation.senia 237415
dc.identifier.eissn 1365-3075
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.description.references Galzerano, P., Agostino, D., Bencivenni, G., Sambri, L., Bartoli, G., & Melchiorre, P. (2010). Controlling Stereoselectivity in the Aminocatalytic Enantioselective Mannich Reaction of Aldehydes with In Situ Generated N-Carbamoyl Imines. Chemistry - A European Journal, 16(20), 6069-6076. doi:10.1002/chem.200903217 es_ES


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