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ELECTROCHEMISTRY AND AUTHENTICATION OF ARCHAEOLOGICAL LEAD USING VOLTAMMETRY OF MICROPARTICLES: APPLICATION TO THE TOSSAL DE SANT MIQUEL IBERIAN PLATE*

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ELECTROCHEMISTRY AND AUTHENTICATION OF ARCHAEOLOGICAL LEAD USING VOLTAMMETRY OF MICROPARTICLES: APPLICATION TO THE TOSSAL DE SANT MIQUEL IBERIAN PLATE*

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dc.contributor.author Domenech Carbo, Antonio es_ES
dc.contributor.author Domenech Carbo, Mª Teresa es_ES
dc.contributor.author Peiró Ronda, María Amparo es_ES
dc.contributor.author Osete Cortina, Laura es_ES
dc.date.accessioned 2015-07-17T07:54:14Z
dc.date.available 2015-07-17T07:54:14Z
dc.date.issued 2011-05
dc.identifier.issn 0003-813X
dc.identifier.uri http://hdl.handle.net/10251/53374
dc.description.abstract An essentially non-invasive electrochemical methodology addressed to the authentication of archaeological lead is described. The method is based on the record of the voltammetric response of nanosamples from the archaeological artefact mechanically transferred to a graphite ‘pencil’ electrode in contact with aqueous buffers. Three diagnostic criteria for authentication are described based on the appearance of: (i) oxidative dissolution signals for trace metals like copper, arsenic, antimony and, often, tin and silver accompanying stripping peaks for lead, (ii) peak potential shifts for reduction peaks for patination products, and (iii) the presence of reduction peaks for PbO2. The method is applied to the authentication of an Iberian lead plate from the Tossal de Sant Miquel (Llíria, Spain) site using a series of genuine and false pieces from different provenances in the Valencian region (Spain). es_ES
dc.description.sponsorship The authors wish to thank the Museu de Prehistoria de Valencia, Museu Arqueologic de Borriana and Museu Municipal de Montcada for the access to their archives and funds. Financial support is gratefully acknowledged from the Spanish 'I+D+I MICINN' project CTQ2008-06727-C03-01 and 02/BQU, supported by ERDEF funds. The authors wish to thank Mr Manuel Planes i Insausti and Dr Jose Luis Moya Lopez, the technical supervisors responsible for the UPV Electron Microscopy Service. en_EN
dc.language Inglés es_ES
dc.publisher Wiley: 24 months es_ES
dc.relation.ispartof Archaeometry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject ARCHAEOLOGICAL LEAD es_ES
dc.subject VOLTAMMETRY OF MICROPARTICLES es_ES
dc.subject AUTHENTICATION es_ES
dc.subject CORROSION PRODUCTS es_ES
dc.subject Electron Microscopy Service of the UPV es_ES
dc.subject.classification PINTURA es_ES
dc.title ELECTROCHEMISTRY AND AUTHENTICATION OF ARCHAEOLOGICAL LEAD USING VOLTAMMETRY OF MICROPARTICLES: APPLICATION TO THE TOSSAL DE SANT MIQUEL IBERIAN PLATE* es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1111/j.1475-4754.2011.00608.x
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2008-06727-C03-01/ES/DESARROLLO DE NUEVOS METODOS DE CONTROL DE TRATAMIENTOS DE LIMPIEZA DE OBRA PICTORICA MEDIANTE ENSAYOS MECANICOS, SEM, AFM, PY-GC-MS, HPLC-EXCLUSION, ESPECTROSCOPIA FTIR Y UV-VIS/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Conservación y Restauración de Bienes Culturales - Departament de Conservació i Restauració de Béns Culturals es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario de Restauración del Patrimonio - Institut Universitari de Restauració del Patrimoni es_ES
dc.description.bibliographicCitation Domenech Carbo, A.; Domenech Carbo, MT.; Peiró Ronda, MA.; Osete Cortina, L. (2011). ELECTROCHEMISTRY AND AUTHENTICATION OF ARCHAEOLOGICAL LEAD USING VOLTAMMETRY OF MICROPARTICLES: APPLICATION TO THE TOSSAL DE SANT MIQUEL IBERIAN PLATE*. Archaeometry. 53(6):1193-1211. https://doi.org/10.1111/j.1475-4754.2011.00608.x es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1111/j.1475-4754.2011.00608.x es_ES
dc.description.upvformatpinicio 1193 es_ES
dc.description.upvformatpfin 1211 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 53 es_ES
dc.description.issue 6 es_ES
dc.relation.senia 214654
dc.identifier.eissn 1475-4754
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder European Regional Development Fund
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