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Combined effect of poly(hydroxybutyrate) and plasticizers on polylactic acid properties for film intended for food packaging

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Combined effect of poly(hydroxybutyrate) and plasticizers on polylactic acid properties for film intended for food packaging

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dc.contributor.author ARRIETA, Marina Patricia es_ES
dc.contributor.author Samper Madrigal, María Dolores es_ES
dc.contributor.author López Martínez, Juan es_ES
dc.contributor.author JIMENEZ MIGALLON, ALFONSO es_ES
dc.date.accessioned 2015-07-24T10:13:13Z
dc.date.available 2015-07-24T10:13:13Z
dc.date.issued 2014-12
dc.identifier.issn 1566-2543
dc.identifier.uri http://hdl.handle.net/10251/53706
dc.description.abstract Poly(lactic acid) PLA, and poly(hydroxybutyrate) PHB, blends were processed as films and characterized for their use in food packaging. PLA was blended with PHB to enhance the crystallinity. Therefore, PHB addition strongly increased oxygen barrier while decreased the wettability. Two different environmentally-friendly plasticizers, poly(ethylene glycol) (PEG) and acetyl(tributyl citrate) (ATBC), were added to these blends to increase their processing performance, while improving their ductile properties. ATBC showed higher plasticizer efficiency than PEG directly related to the similarity solubility parameters between ATBC and both biopolymers. Moreover, ATBC was more efficiently retained to the polymer matrix during processing than PEG. PLA PHB ATBC blends were homogeneous and transparent blends that showed promising performance for the preparation of films by a ready industrial process technology for food packaging applications, showing slightly amber color, improved elongation at break, enhanced oxygen barrier and decreased wettability. es_ES
dc.description.sponsorship This work has been supported by the Spanish Ministry of Economy and Competitiveness (MAT2011-28648-C02-01 and MAT2011-28468-C02-02) M.P. Arrieta is Granted by Santiago Grisolia program (GRISOLIA/2011/007). Authors gratefully acknowledge Prof. Arturo Horta Zubiaga from National University of Distance Education (UNED) Spain for his valuable discussion. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation Spanish Ministry of Economy and Competitiveness [MAT2011-28648-C02-01, MAT2011-28468-C02-02] es_ES
dc.relation Santiago Grisolia program [GRISOLIA/2011/007] es_ES
dc.relation.ispartof Journal of Polymers and the Environment es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Poly(lactic acid) es_ES
dc.subject Poly(hydroxybutyrate) es_ES
dc.subject Blend es_ES
dc.subject Barrier properties es_ES
dc.subject Ductility es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Combined effect of poly(hydroxybutyrate) and plasticizers on polylactic acid properties for film intended for food packaging es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10924-014-0654-y
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Arrieta, MP.; Samper Madrigal, MD.; López Martínez, J.; Jimenez Migallon, A. (2014). Combined effect of poly(hydroxybutyrate) and plasticizers on polylactic acid properties for film intended for food packaging. Journal of Polymers and the Environment. 22(4):460-470. doi:10.1007/s10924-014-0654-y es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10924-014-0654-y es_ES
dc.description.upvformatpinicio 460 es_ES
dc.description.upvformatpfin 470 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 22 es_ES
dc.description.issue 4 es_ES
dc.relation.senia 276790
dc.identifier.eissn 1572-8900
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