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dc.contributor.author | Primo Arnau, Ana María | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.date.accessioned | 2015-11-10T13:30:10Z | |
dc.date.available | 2015-11-10T13:30:10Z | |
dc.date.issued | 2014-11-21 | |
dc.identifier.issn | 0306-0012 | |
dc.identifier.uri | http://hdl.handle.net/10251/57294 | |
dc.description.abstract | [EN] Oil is nowadays the main energy source and this prevalent position most probably will continue in the next decades. This situation is largely due to the degree of maturity that has been achieved in oil refining and petrochemistry as a consequence of the large effort in research and innovation. The remarkable efficiency of oil refining is largely based on the use of zeolites as catalysts. The use of zeolites as catalysts in refining and petrochemistry has been considered as one of the major accomplishments in the chemistry of the XXth century. In this tutorial review, the introductory part describes the main features of zeolites in connection with their use as solid acids. The main body of the review describes important refining processes in which zeolites are used including light naphtha isomerization, olefin alkylation, reforming, cracking and hydrocracking. The final section contains our view on future developments in the field such as the increase in the quality of the transportation fuels and the coprocessing of increasing percentage of biofuels together with oil streams. This review is intended to provide the rudiments of zeolite science applied to refining catalysis. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of Science and Competitiveness (Severo Ochoa and CTQ2012-32315) and Generalidad Valenciana (Prometeo 12/013) is gratefully acknowledged. | |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Chemical Society Reviews | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Temperature-Programmed Desorption | es_ES |
dc.subject | Natural zeolites | es_ES |
dc.subject | Delaminated zeolites | es_ES |
dc.subject | Shape selectivity | es_ES |
dc.subject | Acid strength | es_ES |
dc.subject | Solid acids | es_ES |
dc.subject | Alkylation | es_ES |
dc.subject | Cracking | es_ES |
dc.subject | Chemistry | es_ES |
dc.subject | Ammonia | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Zeolites as catalysts in oil refining | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/C3CS60394F | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F013/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Primo Arnau, AM.; García Gómez, H. (2014). Zeolites as catalysts in oil refining. Chemical Society Reviews. 43(22):7548-7561. https://doi.org/10.1039/C3CS60394F | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c3cs60394f | es_ES |
dc.description.upvformatpinicio | 7548 | es_ES |
dc.description.upvformatpfin | 7561 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 43 | es_ES |
dc.description.issue | 22 | es_ES |
dc.relation.senia | 285587 | es_ES |
dc.identifier.eissn | 1460-4744 | |
dc.identifier.pmid | 24671148 | |
dc.contributor.funder | Ministerio de Economía y Competitividad | |
dc.contributor.funder | Generalitat Valenciana | |
dc.description.references | Rogner, H.-H. (1997). AN ASSESSMENT OF WORLD HYDROCARBON RESOURCES. Annual Review of Energy and the Environment, 22(1), 217-262. doi:10.1146/annurev.energy.22.1.217 | es_ES |
dc.description.references | Shafiee, S., & Topal, E. (2009). When will fossil fuel reserves be diminished? Energy Policy, 37(1), 181-189. doi:10.1016/j.enpol.2008.08.016 | es_ES |
dc.description.references | Edmonds, J., & Reilly, J. (1983). Global energy production and use to the year 2050. Energy, 8(6), 419-432. doi:10.1016/0360-5442(83)90064-6 | es_ES |
dc.description.references | Olah, G. A. (2005). Beyond Oil and Gas: The Methanol Economy. Angewandte Chemie International Edition, 44(18), 2636-2639. doi:10.1002/anie.200462121 | es_ES |
dc.description.references | J. G. Speight , The chemistry and technology of petroleum, CRC Press, 2007 | es_ES |
dc.description.references | Masliyah, J., Zhou, Z. J., Xu, Z., Czarnecki, J., & Hamza, H. (2008). Understanding Water-Based Bitumen Extraction from Athabasca Oil Sands. The Canadian Journal of Chemical Engineering, 82(4), 628-654. doi:10.1002/cjce.5450820403 | es_ES |
dc.description.references | Degnan, T. F. (2003). The implications of the fundamentals of shape selectivity for the development of catalysts for the petroleum and petrochemical industries. Journal of Catalysis, 216(1-2), 32-46. doi:10.1016/s0021-9517(02)00105-7 | es_ES |
dc.description.references | Marcilly, C. R. (2000). Topics in Catalysis, 13(4), 357-366. doi:10.1023/a:1009007021975 | es_ES |
dc.description.references | Corma, A. (1997). From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis. Chemical Reviews, 97(6), 2373-2420. doi:10.1021/cr960406n | es_ES |
dc.description.references | NEWSAM, J. M. (1986). The Zeolite Cage Structure. Science, 231(4742), 1093-1099. doi:10.1126/science.231.4742.1093 | es_ES |
dc.description.references | Cinar, S., & Beler-Baykal, B. (2005). Ion exchange with natural zeolites: an alternative for water softening? Water Science and Technology, 51(11), 71-77. doi:10.2166/wst.2005.0392 | es_ES |
dc.description.references | Erdem, E., Karapinar, N., & Donat, R. (2004). The removal of heavy metal cations by natural zeolites. Journal of Colloid and Interface Science, 280(2), 309-314. doi:10.1016/j.jcis.2004.08.028 | es_ES |
dc.description.references | Navalon, S., Alvaro, M., & Garcia, H. (2010). Heterogeneous Fenton catalysts based on clays, silicas and zeolites. Applied Catalysis B: Environmental, 99(1-2), 1-26. doi:10.1016/j.apcatb.2010.07.006 | es_ES |
dc.description.references | Yamane, I., & Nakazawa, T. (1986). Development of zeolite for non-phosphated detergents in Japan. Pure and Applied Chemistry, 58(10), 1397-1404. doi:10.1351/pac198658101397 | es_ES |
dc.description.references | Blanchard, G., Maunaye, M., & Martin, G. (1984). Removal of heavy metals from waters by means of natural zeolites. Water Research, 18(12), 1501-1507. doi:10.1016/0043-1354(84)90124-6 | es_ES |
dc.description.references | Cooper, E. R., Andrews, C. D., Wheatley, P. S., Webb, P. B., Wormald, P., & Morris, R. E. (2004). Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues. Nature, 430(7003), 1012-1016. doi:10.1038/nature02860 | es_ES |
dc.description.references | Corma, A., Fornés, V., Guil, J. ., Pergher, S., Maesen, T. L. ., & Buglass, J. . (2000). Preparation, characterisation and catalytic activity of ITQ-2, a delaminated zeolite. Microporous and Mesoporous Materials, 38(2-3), 301-309. doi:10.1016/s1387-1811(00)00149-9 | es_ES |
dc.description.references | Corma, A., Fornes, V., Pergher, S. B., Maesen, T. L. M., & Buglass, J. G. (1998). Delaminated zeolite precursors as selective acidic catalysts. Nature, 396(6709), 353-356. doi:10.1038/24592 | es_ES |
dc.description.references | J. Weitkamp , Handbook of heterogeneous catalysis, Gerhard Ertl, 2008 | es_ES |
dc.description.references | Corma, A. (1995). Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions. Chemical Reviews, 95(3), 559-614. doi:10.1021/cr00035a006 | es_ES |
dc.description.references | HIDALGO, C. (1984). Measurement of the acidity of various zeolites by temperature-programmed desorption of ammonia. Journal of Catalysis, 85(2), 362-369. doi:10.1016/0021-9517(84)90225-2 | es_ES |
dc.description.references | Kapustin, G. I., Brueva, T. R., Klyachko, A. L., Beran, S., & Wichterlova, B. (1988). Determination of the number and acid strength of acid sites in zeolites by ammonia adsorption. Applied Catalysis, 42(2), 239-246. doi:10.1016/0166-9834(88)80005-8 | es_ES |
dc.description.references | Corma, A., Fornés, V., Melo, F. V., & Herrero, J. (1987). Comparison of the information given by ammonia t.p.d. and pyridine adsorption—desorption on the acidity of dealuminated HY and LaHY zeolite cracking catalysts. Zeolites, 7(6), 559-563. doi:10.1016/0144-2449(87)90098-4 | es_ES |
dc.description.references | Corma, A., Fornes, V., Navarro, M. T., & Perezpariente, J. (1994). Acidity and Stability of MCM-41 Crystalline Aluminosilicates. Journal of Catalysis, 148(2), 569-574. doi:10.1006/jcat.1994.1243 | es_ES |
dc.description.references | Huang, J., Jiang, Y., Marthala, V. R. R., Bressel, A., Frey, J., & Hunger, M. (2009). Effect of pore size and acidity on the coke formation during ethylbenzene conversion on zeolite catalysts. Journal of Catalysis, 263(2), 277-283. doi:10.1016/j.jcat.2009.02.019 | es_ES |
dc.description.references | Corma, A. (2003). State of the art and future challenges of zeolites as catalysts. Journal of Catalysis, 216(1-2), 298-312. doi:10.1016/s0021-9517(02)00132-x | es_ES |
dc.description.references | Márquez, F., García, H., Palomares, E., Fernández, L., & Corma, A. (2000). Spectroscopic Evidence in Support of the Molecular Orbital Confinement Concept: Case of Anthracene Incorporated in Zeolites. Journal of the American Chemical Society, 122(27), 6520-6521. doi:10.1021/ja0003066 | es_ES |
dc.description.references | Sastre, G., Cano, M. L., Corma, A., García, H., Nicolopoulos, S., González-Calbet, J. M., & Vallet-Regí, M. (1997). On the Incorporation of Buckminsterfullerene C60in the Supercages of Zeolite Y. The Journal of Physical Chemistry B, 101(49), 10184-10190. doi:10.1021/jp963883i | es_ES |
dc.description.references | Bellussi, G., Pazzuconi, G., Perego, C., Girotti, G., & Terzoni, G. (1995). Liquid-Phase Alkylation of Benzene with Light Olefins Catalyzed by β-Zeolites. Journal of Catalysis, 157(1), 227-234. doi:10.1006/jcat.1995.1283 | es_ES |
dc.description.references | BIZREH, Y. (1984). Butane cracking catalyzed by the zeolite H-ZSM-5. Journal of Catalysis, 88(1), 240-243. doi:10.1016/0021-9517(84)90071-x | es_ES |
dc.description.references | KRANNILA, H. (1992). Monomolecular and bimolecular mechanisms of paraffin cracking: n-butane cracking catalyzed by HZSM-5. Journal of Catalysis, 135(1), 115-124. doi:10.1016/0021-9517(92)90273-k | es_ES |
dc.description.references | YOUNG, L. (1982). Shape selective reactions with zeolite catalysts III. Selectivity in xylene isomerization, toluene-methanol alkylation, and toluene disproportionation over ZSM-5 zeolite catalysts. Journal of Catalysis, 76(2), 418-432. doi:10.1016/0021-9517(82)90271-8 | es_ES |
dc.description.references | Haw, J. F. (2002). Zeolite acid strength and reaction mechanisms in catalysis. Phys. Chem. Chem. Phys., 4(22), 5431-5441. doi:10.1039/b206483a | es_ES |
dc.description.references | Xu, T., Munson, E. J., & Haw, J. F. (1994). Toward a Systematic Chemistry of Organic Reactions in Zeolites: In situ NMR Studies of Ketones. Journal of the American Chemical Society, 116(5), 1962-1972. doi:10.1021/ja00084a041 | es_ES |
dc.description.references | S. V. Luis and E.Garcia-Verdugo, Chemical reactions and processes under flow conditions, 2010 | es_ES |
dc.description.references | Arribas, M. A., Márquez, F., & Martı&́nez, A. (2000). Activity, Selectivity, and Sulfur Resistance of Pt/WOx–ZrO2 and Pt/Beta Catalysts for the Simultaneous Hydroisomerization of n-Heptane and Hydrogenation of Benzene. Journal of Catalysis, 190(2), 309-319. doi:10.1006/jcat.2000.2768 | es_ES |
dc.description.references | Corma, A., & Martínez, A. (1993). Chemistry, Catalysts, and Processes for Isoparaffin–Olefin Alkylation: Actual Situation and Future Trends. Catalysis Reviews, 35(4), 483-570. doi:10.1080/01614949308013916 | es_ES |
dc.description.references | Boronat, M., Viruela, P., & Corma, A. (1999). Theoretical Study of Bimolecular Reactions between Carbenium Ions and Paraffins: The Proposal of a Common Intermediate for Hydride Transfer, Disproportionation, Dehydrogenation, and Alkylation. The Journal of Physical Chemistry B, 103(37), 7809-7821. doi:10.1021/jp990987v | es_ES |
dc.description.references | Feller, A., & Lercher, J. A. (2004). Chemistry and Technology of Isobutane/Alkene Alkylation Catalyzed by Liquid and Solid Acids. Advances in Catalysis, 229-295. doi:10.1016/s0360-0564(04)48003-1 | es_ES |
dc.description.references | Corma, A. (2004). Different process schemes for converting light straight run and fluid catalytic cracking naphthas in a FCC unit for maximum propylene production. Applied Catalysis A: General, 265(2), 195-206. doi:10.1016/j.apcata.2004.01.020 | es_ES |
dc.description.references | Martínez, C., & Corma, A. (2011). Inorganic molecular sieves: Preparation, modification and industrial application in catalytic processes. Coordination Chemistry Reviews, 255(13-14), 1558-1580. doi:10.1016/j.ccr.2011.03.014 | es_ES |
dc.description.references | Chen, C.-Y., Li, H.-X., & Davis, M. E. (1993). Studies on mesoporous materials. Microporous Materials, 2(1), 17-26. doi:10.1016/0927-6513(93)80058-3 | es_ES |
dc.description.references | McVicker, G. (2002). Selective Ring Opening of Naphthenic Molecules. Journal of Catalysis, 210(1), 137-148. doi:10.1006/jcat.2002.3685 | es_ES |
dc.description.references | Calemma, V., Ferrari, M., Rabl, S., & Weitkamp, J. (2013). Selective ring opening of naphthenes: From mechanistic studies with a model feed to the upgrading of a hydrotreated light cycle oil. Fuel, 111, 763-770. doi:10.1016/j.fuel.2013.04.055 | es_ES |
dc.description.references | Raichle, A., Traa, Y., Fuder, F., Rupp, M., & Weitkamp, J. (2001). Haag-Dessau Catalysts for Ring Opening of Cycloalkanes. Angewandte Chemie International Edition, 40(7), 1243-1246. doi:10.1002/1521-3773(20010401)40:7<1243::aid-anie1243>3.0.co;2-7 | es_ES |