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Efficient one-pot preparation of Cu-SSZ-13 materials using cooperative OSDAs for their catalytic applications in the SCR of NOx

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Efficient one-pot preparation of Cu-SSZ-13 materials using cooperative OSDAs for their catalytic applications in the SCR of NOx

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dc.contributor.author Martínez Franco, Raquel es_ES
dc.contributor.author Moliner Marin, Manuel es_ES
dc.contributor.author Thogersen, Joakim R. es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2015-11-18T13:17:20Z
dc.date.issued 2013-11
dc.identifier.issn 1867-3880
dc.identifier.uri http://hdl.handle.net/10251/57690
dc.description.abstract The cooperative use of the Cu-tetraethylenepentamine complex and N,N,N-trimethyl-1-adamantammonium as organic structure-directing agents (OSDAs) enabled the rationalized one-pot preparation of Cu-containing SSZ-13 zeolites. A detailed study of different synthetic variables permitted the control of the Si/Al and Cu/(Si+Al) ratios in the final solids. Cu-SSZ-13 molecular sieves synthesized in alkaline media demonstrate excellent catalytic activities and good hydrothermal stabilities for the selective catalytic reduction of NOx. Finally, the effect of synthesis media on the catalytic active sites is also demonstrated and a remarkable activity loss for samples synthesized in fluoride media is observed. es_ES
dc.description.sponsorship This work has been supported by Haldor-Topsoe, the Spanish Government-MINECO (MAT2012-37160), Consolider Ingenio 2010-Multicat, and UPV through PAID-06-11 (n. 1952). M.M. also acknowledges the "Subprograma Ramon y Cajal" for the contract RYC-2011-08972. The Instituto de Tecnologia Quimica thanks the "Program Severo Ochoa" for financial support (SEV 2012 0267). The authors thank Isabel Millet for technical support. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject copper es_ES
dc.subject hydrothermal stability es_ES
dc.subject nitrogen oxides es_ES
dc.subject selective catalytic reduction es_ES
dc.subject zeolites es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Efficient one-pot preparation of Cu-SSZ-13 materials using cooperative OSDAs for their catalytic applications in the SCR of NOx es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cctc.201300141
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2012-37160/ES/SINTESIS DE NUEVOS MATERIALES MICROPOROSOS BASADOS EN EL USO DE ?ESPONJAS DE PROTONES? COMO AGENTES DIRECTORES DE ESTRUCTURA (ADES)/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-06-11-1952/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//RYC-2011-08972/ES/RYC-2011-08972/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Martínez Franco, R.; Moliner Marin, M.; Thogersen, JR.; Corma Canós, A. (2013). Efficient one-pot preparation of Cu-SSZ-13 materials using cooperative OSDAs for their catalytic applications in the SCR of NOx. ChemCatChem. 5(11):3316-3323. https://doi.org/10.1002/cctc.201300141 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cctc.201300141 es_ES
dc.description.upvformatpinicio 3316 es_ES
dc.description.upvformatpfin 3323 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.description.issue 11 es_ES
dc.relation.senia 258637 es_ES
dc.identifier.eissn 1867-3899
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Haldor Topsøe es_ES
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