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One-Pot Multifunctional Catalysis with NNN-Pincer Zr-MOF: Zr Base Catalyzed Condensation with Rh-Catalyzed Hydrogenation

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One-Pot Multifunctional Catalysis with NNN-Pincer Zr-MOF: Zr Base Catalyzed Condensation with Rh-Catalyzed Hydrogenation

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dc.contributor.author Rasero Almansa, Antonia Maria es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Iglesias, Marta es_ES
dc.contributor.author Sánchez Alonso, Felix es_ES
dc.date.accessioned 2015-11-18T13:28:32Z
dc.date.issued 2013-10
dc.identifier.issn 1867-3880
dc.identifier.uri http://hdl.handle.net/10251/57691
dc.description.abstract We describe the postsynthetic modification of Zr-based metal organic frameworks (MOFs) containing chiral NNN-pincer ligands based on aminopyridineimines, as well as the subsequent formation of (NNN)-M-Zr-MOF complexes (M=Rh, Ir). With these new multifunctional materials, we performed a cascade of condensation reactions followed by hydrogenation of the resulting double bond. If the condensation reaction occurs between an aldehyde and ethyl nitroacetate, (NNN)-M-Zr-MOF complexes catalyze the one-pot synthesis of nitroalkenes, in which Zr-IV Lewis sites play a role similar to that of the generally used Ti-IV in homogeneous catalysis. These multifunctional hybrid catalysts retain their crystalline framework even after the reaction, and they were isolated easily from the reaction mixture through filtration and reused several times without a significant degradation in activity. Moreover, there was no contribution from leached active species and conversion was possible only in the presence of the solid catalyst. es_ES
dc.description.sponsorship We thank the Ministerio de Economia y Competitividad (MINECO) of Spain (project no. MAT2011-29020-C02-02) and Consolider-Ingenio 2010 Program (CSD-0050-MULTICAT) for the financial support. A.M.R.-A. thanks MINECO for the FPI program. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject domino reactions es_ES
dc.subject heterogenized catalysts es_ES
dc.subject metal organic frameworks es_ES
dc.subject postfunctionalization es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title One-Pot Multifunctional Catalysis with NNN-Pincer Zr-MOF: Zr Base Catalyzed Condensation with Rh-Catalyzed Hydrogenation es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cctc.201300371
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-02/ES/MATERIALES HIBRIDOS ORGANO-INORGANICOS COMO CATALIZADORES SELECTIVOS RECICLABLES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ / es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Rasero Almansa, AM.; Corma Canós, A.; Iglesias, M.; Sánchez Alonso, F. (2013). One-Pot Multifunctional Catalysis with NNN-Pincer Zr-MOF: Zr Base Catalyzed Condensation with Rh-Catalyzed Hydrogenation. ChemCatChem. 5(10):3092-3100. https://doi.org/10.1002/cctc.201300371 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cctc.201300371 es_ES
dc.description.upvformatpinicio 3092 es_ES
dc.description.upvformatpfin 3100 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.description.issue 10 es_ES
dc.relation.senia 258652 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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