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Selective reductive coupling of nitro compounds with aldehydes to nitrones in H2 using carbon-supported and decorated platinum nanoparticle

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Selective reductive coupling of nitro compounds with aldehydes to nitrones in H2 using carbon-supported and decorated platinum nanoparticle

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dc.contributor.author Cisneros Reyes, Larisha Yanira es_ES
dc.contributor.author Serna Merino, Pedro Manuel es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2016-01-18T09:28:29Z
dc.date.issued 2014-08-25
dc.identifier.issn 1433-7851
dc.identifier.uri http://hdl.handle.net/10251/59968
dc.description.abstract Nitrones were synthesized in high yields directly from nitro compounds, aldehydes, and H-2 using carbon-decorated platinum nanoparticles. The high selectivity for nitrone synthesis contrasts that of common supported metal catalysts and corresponds to an increase from roughly 6 to 97%. The catalytic performance is tuned by precise control of the structure of the active sites and the characteristics of the support. es_ES
dc.description.sponsorship The research was supported by Project CONSOLIDER INGENIO (MULTICAT), PROMETEO, the SEVERO OCHOA Program for centers of excellence, the "Subprograma Ramon y Cajal" (contract RYC-2012-10662 to P.S.), and the CONACyT Program (fellowship to L.C.). en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject cascade reactions es_ES
dc.subject hydrogenation es_ES
dc.subject supported catalysts es_ES
dc.subject nitrones es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Selective reductive coupling of nitro compounds with aldehydes to nitrones in H2 using carbon-supported and decorated platinum nanoparticle es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/anie.201402878
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//RYC-2012-10662/ES/RYC-2012-10662/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Cisneros Reyes, LY.; Serna Merino, PM.; Corma Canós, A. (2014). Selective reductive coupling of nitro compounds with aldehydes to nitrones in H2 using carbon-supported and decorated platinum nanoparticle. Angewandte Chemie International Edition. 53(35):9306-9310. https://doi.org/10.1002/anie.201402878 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/anie.201402878 es_ES
dc.description.upvformatpinicio 9306 es_ES
dc.description.upvformatpfin 9310 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 53 es_ES
dc.description.issue 35 es_ES
dc.relation.senia 282681 es_ES
dc.identifier.eissn 1521-3773
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Consejo Nacional de Ciencia y Tecnología, México
dc.contributor.funder Generalitat Valenciana
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