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Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides

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Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides

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Grirrane ., A.; Álvarez, E.; García Gómez, H.; Corma Canós, A. (2014). Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides. Angewandte Chemie International Edition. 53(28):7253-7258. https://doi.org/10.1002/anie.201403973

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/59971

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Título: Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides
Autor: Grirrane ., Abdessamad Álvarez, Eleuterio García Gómez, Hermenegildo Corma Canós, Avelino
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
Care should be exercised when using CH2Cl2 as a solvent for reactions in which amines are a reagent, since undesirable deactivation of cationic copper(I) and gold( I) catalysts to form the corresponding inactive neutral ...[+]
Palabras clave: coordination chemistry , copper intermediates , gold intermediates , homogeneous catalysis , propargylamines
Derechos de uso: Cerrado
Fuente:
Angewandte Chemie International Edition. (issn: 1433-7851 ) (eissn: 1521-3773 )
DOI: 10.1002/anie.201403973
Editorial:
Wiley-VCH Verlag
Versión del editor: http://dx.doi.org/10.1002/anie.201403973
Código del Proyecto:
info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/
info:eu-repo/grantAgreement/GVA//GV%2F2012%2F014/
Agradecimientos:
Financial support by the Spanish Ministry of the Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and the Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged.
Tipo: Artículo

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