- -

Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides

Show full item record

Grirrane ., A.; Álvarez, E.; García Gómez, H.; Corma Canós, A. (2014). Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides. Angewandte Chemie International Edition. 53(28):7253-7258. doi:10.1002/anie.201403973

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/59971

Files in this item

Item Metadata

Title: Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
Care should be exercised when using CH2Cl2 as a solvent for reactions in which amines are a reagent, since undesirable deactivation of cationic copper(I) and gold( I) catalysts to form the corresponding inactive neutral ...[+]
Subjects: coordination chemistry , copper intermediates , gold intermediates , homogeneous catalysis , propargylamines
Copyrigths: Cerrado
Source:
Angewandte Chemie International Edition. (issn: 1433-7851 ) (eissn: 1521-3773 )
DOI: 10.1002/anie.201403973
Publisher:
Wiley-VCH Verlag
Publisher version: http://dx.doi.org/10.1002/anie.201403973
Thanks:
Financial support by the Spanish Ministry of the Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and the Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged.
Type: Artículo

This item appears in the following Collection(s)

Show full item record