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dc.contributor.author | Grirrane ., Abdessamad | es_ES |
dc.contributor.author | Álvarez, Eleuterio | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2016-01-18T09:50:46Z | |
dc.date.issued | 2014-07 | |
dc.identifier.issn | 1433-7851 | |
dc.identifier.uri | http://hdl.handle.net/10251/59971 | |
dc.description.abstract | Care should be exercised when using CH2Cl2 as a solvent for reactions in which amines are a reagent, since undesirable deactivation of cationic copper(I) and gold( I) catalysts to form the corresponding inactive neutral chloride complexes [LMCl] (M=Cu or Au) can occur as a result of the generation of hydrogen chloride in the medium. Cu-I and Au-I deactivation has been proved for the Mannich three-component coupling reaction. A series of CuI and AuI complexes with potential mechanistic implications were isolated and characterized by X-ray crystallography. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of the Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and the Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-VCH Verlag | es_ES |
dc.relation.ispartof | Angewandte Chemie International Edition | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | coordination chemistry | es_ES |
dc.subject | copper intermediates | es_ES |
dc.subject | gold intermediates | es_ES |
dc.subject | homogeneous catalysis | es_ES |
dc.subject | propargylamines | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1002/anie.201403973 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//GV%2F2012%2F014/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Grirrane ., A.; Álvarez, E.; García Gómez, H.; Corma Canós, A. (2014). Deactivation of Cationic Cu-I and Au-I Catalysts for A(3) Coupling by CH2Cl2 : Mechanistic Implications of the Formation of Neutral Cu-I and Au-I Chlorides. Angewandte Chemie International Edition. 53(28):7253-7258. https://doi.org/10.1002/anie.201403973 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/anie.201403973 | es_ES |
dc.description.upvformatpinicio | 7253 | es_ES |
dc.description.upvformatpfin | 7258 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 53 | es_ES |
dc.description.issue | 28 | es_ES |
dc.relation.senia | 282053 | es_ES |
dc.identifier.eissn | 1521-3773 | |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
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