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Copper Nanoparticles Supported on Doped Graphenes as Catalyst for the Dehydrogenative Coupling of Silanes and Alcohols

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Copper Nanoparticles Supported on Doped Graphenes as Catalyst for the Dehydrogenative Coupling of Silanes and Alcohols

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dc.contributor.author Blandez Barradas, Juan Francisco es_ES
dc.contributor.author Primo Arnau, Ana María es_ES
dc.contributor.author Asiri, Abdullah es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2016-01-18T09:56:26Z
dc.date.issued 2014-11-10
dc.identifier.issn 1433-7851
dc.identifier.uri http://hdl.handle.net/10251/59972
dc.description.abstract [EN] Copper nanoparticles (NPs) supported on a series of undoped and doped graphene materials (Gs) have been obtained by pyrolysis of alginate or chitosan biopolymers, modified or not with boric acid, containing Cu2+ ions at 900 8C under inert atmosphere. The resulting Cu-G materials containing about 17 wt% Cu NPs (from 10 to 200 nm) exhibit high catalytic activity for the dehydrogenative coupling of silanes with alcohols. The optimal material consisting on Cu- (B)G is more efficient than Cu NPs on other carbon supports es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of economy and competitiveness (Severo Ochoa and CTQ2012-32315) and Generalitat Valenciana Prometeo 2012-013) is gratefully acknowledged.
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Alcoxysilanes es_ES
dc.subject Dehydrogenative coupling es_ES
dc.subject Graphene es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Metal nanoparticles es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Copper Nanoparticles Supported on Doped Graphenes as Catalyst for the Dehydrogenative Coupling of Silanes and Alcohols es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/anie.201405669
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F013/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Blandez Barradas, JF.; Primo Arnau, AM.; Asiri, A.; Alvaro Rodríguez, MM.; García Gómez, H. (2014). Copper Nanoparticles Supported on Doped Graphenes as Catalyst for the Dehydrogenative Coupling of Silanes and Alcohols. Angewandte Chemie International Edition. 53(46):12581-12586. https://doi.org/10.1002/anie.201405669 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/anie.201405669 es_ES
dc.description.upvformatpinicio 12581 es_ES
dc.description.upvformatpfin 12586 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 53 es_ES
dc.description.issue 46 es_ES
dc.relation.senia 278553 es_ES
dc.identifier.eissn 1521-3773
dc.identifier.pmid 25196304
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder Generalitat Valenciana
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