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Passivity Breakdown of Titanium in LiBr solutions

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Passivity Breakdown of Titanium in LiBr solutions

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dc.contributor.author Fernández Domene, Ramón Manuel es_ES
dc.contributor.author Blasco-Tamarit, E. es_ES
dc.contributor.author García-García, D.M. es_ES
dc.contributor.author García Antón, José es_ES
dc.date.accessioned 2016-02-03T15:38:05Z
dc.date.available 2016-02-03T15:38:05Z
dc.date.issued 2014
dc.identifier.issn 0013-4651
dc.identifier.uri http://hdl.handle.net/10251/60567
dc.description.abstract The passive behavior of titanium and its susceptibility to undergo localized attack in different LiBr solutions at 25 degrees C have been investigated using different electrochemical techniques: potentiodynamic polarization curves, potentiostatic passivation tests, EIS measurements and Mott-Schottky analysis. In low and moderately concentrated LiBr solutions, the breakdown potential E-b decreased with increasing bromide concentrations, while in highly concentrated LiBr solutions, E-b increased with increasing LiBr concentration. In the most concentrated LiBr solution (11.42M) Ti did not undergo passivity breakdown even at 9 V-Ag/AgCl. This observation can be explained by a a decrease in the activity of water in highly concentrated LiBr solutions. (C) 2013 The Electrochemical Society. es_ES
dc.description.sponsorship We wish express our gratitude to the Ministerio de Ciencia e Innovacion (Project CTQ2009-07518), and to Dr. M. Asuncion Jaime. for her translation assistance. en_EN
dc.language Inglés es_ES
dc.publisher Electrochemical Society es_ES
dc.relation.ispartof Journal of The Electrochemical Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Passivity breakdown es_ES
dc.subject Titanium es_ES
dc.subject LiBr es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Passivity Breakdown of Titanium in LiBr solutions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1149/2.035401jes
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2009-07518/ES/ESTUDIO DE LA CORROSION TERMOGALVANICA EN LAS MAQUINAS DE ABSORCION DE LIBR DE DOBLE EFECTO MEDIANTE TECNICAS ELECTROQUIMICAS Y DE IMAGEN/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Seguridad Industrial, Radiofísica y Medioambiental - Institut de Seguretat Industrial, Radiofísica i Mediambiental es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Fernández Domene, RM.; Blasco-Tamarit, E.; García-García, D.; García Antón, J. (2014). Passivity Breakdown of Titanium in LiBr solutions. Journal of The Electrochemical Society. 161(1):25-35. https://doi.org/10.1149/2.035401jes es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1149/2.035401jes es_ES
dc.description.upvformatpinicio 25 es_ES
dc.description.upvformatpfin 35 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 161 es_ES
dc.description.issue 1 es_ES
dc.relation.senia 252247 es_ES
dc.identifier.eissn 1945-7111
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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