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Passive Behavior and Passivity Breakdown of AISI 304 in LiBr Solutions through Scanning Electrochemical Microscopy

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Passive Behavior and Passivity Breakdown of AISI 304 in LiBr Solutions through Scanning Electrochemical Microscopy

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dc.contributor.author Fernández Domene, Ramón Manuel es_ES
dc.contributor.author Sánchez Tovar, Rita es_ES
dc.contributor.author García Antón, José es_ES
dc.date.accessioned 2016-02-05T08:00:06Z
dc.date.available 2016-02-05T08:00:06Z
dc.date.issued 2014
dc.identifier.issn 0013-4651
dc.identifier.uri http://hdl.handle.net/10251/60649
dc.description.abstract The passive behavior and passivity breakdown of AISI 304 stainless steel in LiBr solutions has been investigated by means of scanning electrochemical microscopy (SECM). The sample generation - tip collection (SG-TC) mode was used to operate the SECM and the tip potential was biased to detect the electroactive species. The evolution of the current at the ultramicroelectrode tip with the applied potential within the passive range was followed at different LiBr concentrations. Results show that the absolute value of the current at the tip increases with the applied potential. Additionally, SECM was also used to detect stable pits formed on the stainless steel surface in a 0.2 M LiBr solution. The results show clear evidence of the presence of high amounts of other reducible species (metal cations) apart from oxygen. Also, the dish-shape morphology of the pits observed using Confocal Laser Scanning Microscopy will be discussed in relation to the kinetics of the reactions observed using SECM. (c) 2014 The Electrochemical Society. All rights reserved. es_ES
dc.description.sponsorship The authors would like to express their gratitude to the Generalitat Valenciana for its help in the SECM acquisition (PPC/2011/013) and in the CLSM acquisition (MY08/ISIRM/S/100) and to Dr. Asuncion Jaime for her translation assistance. en_EN
dc.language Inglés es_ES
dc.publisher Electrochemical Society es_ES
dc.relation.ispartof Journal of The Electrochemical Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject AUSTENITIC-STAINLESS-STEELS es_ES
dc.subject METALS-BASED CIVILIZATION es_ES
dc.subject PITTING CORROSION es_ES
dc.subject SEMICONDUCTING PROPERTIES es_ES
dc.subject DEGRADATION PROCESSES es_ES
dc.subject LOCALIZED CORROSION es_ES
dc.subject COATED METALS es_ES
dc.subject OXIDE-FILMS es_ES
dc.subject IN-SITU es_ES
dc.subject ELECTRONIC-STRUCTURE es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Passive Behavior and Passivity Breakdown of AISI 304 in LiBr Solutions through Scanning Electrochemical Microscopy es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1149/2.1051412jes
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PPC%2F2011%2F013/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//MY08%2FISIRM%2FS%2F100/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Seguridad Industrial, Radiofísica y Medioambiental - Institut de Seguretat Industrial, Radiofísica i Mediambiental es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Fernández Domene, RM.; Sánchez Tovar, R.; García Antón, J. (2014). Passive Behavior and Passivity Breakdown of AISI 304 in LiBr Solutions through Scanning Electrochemical Microscopy. Journal of The Electrochemical Society. 161(12):565-572. https://doi.org/10.1149/2.1051412jes es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1149/2.1051412jes es_ES
dc.description.upvformatpinicio 565 es_ES
dc.description.upvformatpfin 572 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 161 es_ES
dc.description.issue 12 es_ES
dc.relation.senia 278759 es_ES
dc.identifier.eissn 1945-7111
dc.contributor.funder Generalitat Valenciana es_ES
dc.description.references Cobb Harold M. (Ed.), Steel Products Manual: Stainless Steels, Iron & Steel Society, 1999. es_ES
dc.description.references Schweitzer P. A. , Corrosion Engineering Handbook: Fundamentals of Metallic Corrosion, CRC Press, Boca Ratón, FL., 2007. es_ES
dc.description.references Hakiki, N. B., Boudin, S., Rondot, B., & Da Cunha Belo, M. (1995). The electronic structure of passive films formed on stainless steels. Corrosion Science, 37(11), 1809-1822. doi:10.1016/0010-938x(95)00084-w es_ES
dc.description.references Wijesinghe, T. L. S. L., & Blackwood, D. J. (2008). Photocurrent and capacitance investigations into the nature of the passive films on austenitic stainless steels. Corrosion Science, 50(1), 23-34. doi:10.1016/j.corsci.2007.06.009 es_ES
dc.description.references Hakiki, N. E. (1998). Semiconducting Properties of Passive Films Formed on Stainless Steels. Journal of The Electrochemical Society, 145(11), 3821. doi:10.1149/1.1838880 es_ES
dc.description.references Olefjord, I. (1985). Surface Composition of Stainless Steels during Anodic Dissolution and Passivation Studied by ESCA. Journal of The Electrochemical Society, 132(12), 2854. doi:10.1149/1.2113683 es_ES
dc.description.references Lothongkum, G., Chaikittisilp, S., & Lothongkum, A. . (2003). XPS investigation of surface films on high Cr-Ni ferritic and austenitic stainless steels. Applied Surface Science, 218(1-4), 203-210. doi:10.1016/s0169-4332(03)00600-7 es_ES
dc.description.references Freire, L., Carmezim, M. J., Ferreira, M. G. S., & Montemor, M. F. (2010). The passive behaviour of AISI 316 in alkaline media and the effect of pH: A combined electrochemical and analytical study. Electrochimica Acta, 55(21), 6174-6181. doi:10.1016/j.electacta.2009.10.026 es_ES
dc.description.references Roberge P. R. , Corrosion Engineering. Principles and Practice, 1st. ed., McGraw-Hill, New York, NY, 2008. es_ES
dc.description.references Wipf, D. O. (1994). Initiation and study of localized corrosion by scanning electrochemical microscopy. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 93, 251-261. doi:10.1016/0927-7757(94)02872-9 es_ES
dc.description.references Casillas, N. (1994). Pitting Corrosion of Titanium. Journal of The Electrochemical Society, 141(3), 636. doi:10.1149/1.2054783 es_ES
dc.description.references Basame, S. B., & White, H. S. (1995). Scanning electrochemical microscopy of native titanium oxide films. Mapping the potential dependence of spatially-localized electrochemical reactions. The Journal of Physical Chemistry, 99(44), 16430-16435. doi:10.1021/j100044a034 es_ES
dc.description.references Still, J. W. (1997). Breakdown of the Iron Passive Layer by Use of the Scanning Electrochemical Microscope. Journal of The Electrochemical Society, 144(8), 2657. doi:10.1149/1.1837879 es_ES
dc.description.references Zhu, Y. (1997). Scanning Electrochemical Microscopic Observation of a Precursor State to Pitting Corrosion of Stainless Steel. Journal of The Electrochemical Society, 144(3), L43. doi:10.1149/1.1837487 es_ES
dc.description.references Basame, S. B., & White, H. S. (1998). Scanning Electrochemical Microscopy:  Measurement of the Current Density at Microscopic Redox-Active Sites on Titanium. The Journal of Physical Chemistry B, 102(49), 9812-9819. doi:10.1021/jp982088x es_ES
dc.description.references Williams, D. E. (1998). Elucidation of a Trigger Mechanism for Pitting Corrosion of Stainless Steels Using Submicron Resolution Scanning Electrochemical and Photoelectrochemical Microscopy. Journal of The Electrochemical Society, 145(8), 2664. doi:10.1149/1.1838697 es_ES
dc.description.references Lister, T. E., & Pinhero, P. J. (2002). Scanning Electrochemical Microscopy Study of Corrosion Dynamics on Type 304 Stainless Steel. Electrochemical and Solid-State Letters, 5(11), B33. doi:10.1149/1.1510621 es_ES
dc.description.references Lister, T. E., & Pinhero, P. J. (2003). The effect of localized electric fields on the detection of dissolved sulfur species from Type 304 stainless steel using scanning electrochemical microscopy. Electrochimica Acta, 48(17), 2371-2378. doi:10.1016/s0013-4686(03)00228-7 es_ES
dc.description.references González-Garcı́a, Y., Burstein, G. ., González, S., & Souto, R. . (2004). Imaging metastable pits on austenitic stainless steel in situ at the open-circuit corrosion potential. Electrochemistry Communications, 6(7), 637-642. doi:10.1016/j.elecom.2004.04.018 es_ES
dc.description.references Souto, R. M., González-Garcı́a, Y., & González, S. (2005). In situ monitoring of electroactive species by using the scanning electrochemical microscope. Application to the investigation of degradation processes at defective coated metals. Corrosion Science, 47(12), 3312-3323. doi:10.1016/j.corsci.2005.07.005 es_ES
dc.description.references Völker, E., Inchauspe, C. G., & Calvo, E. J. (2006). Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel. Electrochemistry Communications, 8(1), 179-183. doi:10.1016/j.elecom.2005.10.003 es_ES
dc.description.references Gabrielli, C., Joiret, S., Keddam, M., Perrot, H., Portail, N., Rousseau, P., & Vivier, V. (2007). A SECM assisted EQCM study of iron pitting. Electrochimica Acta, 52(27), 7706-7714. doi:10.1016/j.electacta.2007.03.008 es_ES
dc.description.references Yin, Y., Niu, L., Lu, M., Guo, W., & Chen, S. (2009). In situ characterization of localized corrosion of stainless steel by scanning electrochemical microscope. Applied Surface Science, 255(22), 9193-9199. doi:10.1016/j.apsusc.2009.07.003 es_ES
dc.description.references Santana, J. J., González-Guzmán, J., Fernández-Mérida, L., González, S., & Souto, R. M. (2010). Visualization of local degradation processes in coated metals by means of scanning electrochemical microscopy in the redox competition mode. Electrochimica Acta, 55(15), 4488-4494. doi:10.1016/j.electacta.2010.02.091 es_ES
dc.description.references González-García, Y., Santana, J. J., González-Guzmán, J., Izquierdo, J., González, S., & Souto, R. M. (2010). Scanning electrochemical microscopy for the investigation of localized degradation processes in coated metals. Progress in Organic Coatings, 69(2), 110-117. doi:10.1016/j.porgcoat.2010.04.006 es_ES
dc.description.references Yuan, Y., Li, L., Wang, C., & Zhu, Y. (2010). Study of the effects of hydrogen on the pitting processes of X70 carbon steel with SECM. Electrochemistry Communications, 12(12), 1804-1807. doi:10.1016/j.elecom.2010.10.031 es_ES
dc.description.references Aouina, N., Balbaud-Célérier, F., Huet, F., Joiret, S., Perrot, H., Rouillard, F., & Vivier, V. (2011). Single pit initiation on 316L austenitic stainless steel using scanning electrochemical microscopy. Electrochimica Acta, 56(24), 8589-8596. doi:10.1016/j.electacta.2011.07.044 es_ES
dc.description.references Bard A. J. Mirkin M. V. (Eds.), Scanning Electrochemical Microscopy, 1st. ed., Marcel Dekker, New York, NJ, 2001. es_ES
dc.description.references Kaneko, M., & Isaacs, H. . (2000). Pitting of stainless steel in bromide, chloride and bromide/chloride solutions. Corrosion Science, 42(1), 67-78. doi:10.1016/s0010-938x(99)00056-6 es_ES
dc.description.references Frankel, G. S. (1998). Pitting Corrosion of Metals. Journal of The Electrochemical Society, 145(6), 2186. doi:10.1149/1.1838615 es_ES
dc.description.references Kaneko, M., & Isaacs, H. S. (2002). Effects of molybdenum on the pitting of ferritic- and austenitic-stainless steels in bromide and chloride solutions. Corrosion Science, 44(8), 1825-1834. doi:10.1016/s0010-938x(02)00003-3 es_ES
dc.description.references Abd El Meguid, E. A., & Mahmoud, N. A. (2003). Inhibition of Bromide-Pitting Corrosion of Type 904L Stainless Steel. CORROSION, 59(2), 104-111. doi:10.5006/1.3277539 es_ES
dc.description.references Anderko, A., & Young, R. D. (2000). Model for Corrosion of Carbon Steel in Lithium Bromide Absorption Refrigeration Systems. CORROSION, 56(5), 543-555. doi:10.5006/1.3280559 es_ES
dc.description.references Chau, D. S., Wood, B. D., Berman, N. S., & Kim, K. J. (1993). Solubility of oxygen in aqueous lithium bromide using electrochemical technique. International Communications in Heat and Mass Transfer, 20(5), 643-652. doi:10.1016/0735-1933(93)90076-8 es_ES
dc.description.references Macdonald, D. D. (1992). The Point Defect Model for the Passive State. Journal of The Electrochemical Society, 139(12), 3434. doi:10.1149/1.2069096 es_ES
dc.description.references Paola, A. D. (1989). Semiconducting properties of passive films on stainless steels. Electrochimica Acta, 34(2), 203-210. doi:10.1016/0013-4686(89)87086-0 es_ES
dc.description.references Hakiki, N. E., Montemor, M. F., Ferreira, M. G. S., & da Cunha Belo, M. (2000). Semiconducting properties of thermally grown oxide films on AISI 304 stainless steel. Corrosion Science, 42(4), 687-702. doi:10.1016/s0010-938x(99)00082-7 es_ES
dc.description.references Carmezim, M. J., Simões, A. M., Figueiredo, M. O., & Da Cunha Belo, M. (2002). Electrochemical behaviour of thermally treated Cr-oxide films deposited on stainless steel. Corrosion Science, 44(3), 451-465. doi:10.1016/s0010-938x(01)00076-2 es_ES
dc.description.references Sharma S. K. , Green Corrosion Chemistry and Engineering: Opportunities and Challenges, Wiley-VCH Verlag GmbH & Co., First Edition, Germany, 2012. es_ES
dc.description.references Venkatraman, M. S., Cole, I. S., & Emmanuel, B. (2011). Corrosion under a porous layer: A porous electrode model and its implications for self-repair. Electrochimica Acta, 56(24), 8192-8203. doi:10.1016/j.electacta.2011.06.020 es_ES
dc.description.references Thomas, S., Cole, I. S., Sridhar, M., & Birbilis, N. (2013). Revisiting zinc passivation in alkaline solutions. Electrochimica Acta, 97, 192-201. doi:10.1016/j.electacta.2013.03.008 es_ES
dc.description.references Gao, S., Dong, C., Luo, H., Xiao, K., Pan, X., & Li, X. (2013). Scanning electrochemical microscopy study on the electrochemical behavior of CrN film formed on 304 stainless steel by magnetron sputtering. Electrochimica Acta, 114, 233-241. doi:10.1016/j.electacta.2013.10.009 es_ES
dc.description.references Lu, G., Cooper, J. S., & McGinn, P. J. (2007). SECM imaging of electrocatalytic activity for oxygen reduction reaction on thin film materials. Electrochimica Acta, 52(16), 5172-5181. doi:10.1016/j.electacta.2007.02.022 es_ES
dc.description.references Song C. Zhang J. , Electrocatalytic Oxygen Reduction Reaction, in: J. Zhang (Ed.), PEM Fuel Cell Electrocatalysts and Catalyst Layers, Ch. 2, Springer, London, 2008, p. 89. es_ES
dc.description.references Macdonald, D. D. (1999). Passivity–the key to our metals-based civilization. Pure and Applied Chemistry, 71(6), 951-978. doi:10.1351/pac199971060951 es_ES
dc.description.references Macdonald, D. D., Rifaie, M. A., & Engelhardt, G. R. (2001). New Rate Laws for the Growth and Reduction of Passive Films. Journal of The Electrochemical Society, 148(9), B343. doi:10.1149/1.1385818 es_ES
dc.description.references Macdonald, D. D. (2006). On the Existence of Our Metals-Based Civilization. Journal of The Electrochemical Society, 153(7), B213. doi:10.1149/1.2195877 es_ES
dc.description.references Marconnet, C., Wouters, Y., Miserque, F., Dagbert, C., Petit, J.-P., Galerie, A., & Féron, D. (2008). Chemical composition and electronic structure of the passive layer formed on stainless steels in a glucose-oxidase solution. Electrochimica Acta, 54(1), 123-132. doi:10.1016/j.electacta.2008.02.070 es_ES
dc.description.references Rhode, S., Kain, V., Raja, V. S., & Abraham, G. J. (2013). Factors affecting corrosion behavior of inclusion containing stainless steels: A scanning electrochemical microscopic study. Materials Characterization, 77, 109-115. doi:10.1016/j.matchar.2013.01.006 es_ES
dc.description.references Newman, R. C., & Franz, E. M. (1984). Growth and Repassivation of Single Corrosion Pits in Stainless Steel. CORROSION, 40(7), 325-330. doi:10.5006/1.3593930 es_ES
dc.description.references Simões, A. M., Bastos, A. C., Ferreira, M. G., González-García, Y., González, S., & Souto, R. M. (2007). Use of SVET and SECM to study the galvanic corrosion of an iron–zinc cell. Corrosion Science, 49(2), 726-739. doi:10.1016/j.corsci.2006.04.021 es_ES
dc.description.references Beck, T. R. (1979). Occurrence of Salt Films during Initiation and Growth of Corrosion Pits. Journal of The Electrochemical Society, 126(10), 1662. doi:10.1149/1.2128772 es_ES
dc.description.references Alkire, R. C., & Wong, K. P. (1988). The corrosion of single pits on stainless steel in acidic chloride solution. Corrosion Science, 28(4), 411-421. doi:10.1016/0010-938x(88)90060-1 es_ES
dc.description.references Bastos, A. C., Simões, A. M., González, S., González-García, Y., & Souto, R. M. (2004). Imaging concentration profiles of redox-active species in open-circuit corrosion processes with the scanning electrochemical microscope. Electrochemistry Communications, 6(11), 1212-1215. doi:10.1016/j.elecom.2004.09.022 es_ES
dc.description.references Böhni H. , Localized Corrosion of Passive Metals, in: Winston Revie R. (Ed.), Uhlig's Corrosion Handbook, 2nd ed., Ch. 10, Wiley Interscience, New York, 2000. es_ES
dc.description.references Leiva-García, R., García-Antón, J., & Muñoz-Portero, M. J. (2010). Contribution to the elucidation of corrosion initiation through confocal laser scanning microscopy (CLSM). Corrosion Science, 52(6), 2133-2142. doi:10.1016/j.corsci.2010.02.034 es_ES
dc.description.references Laycock, N. J., & Newman, R. C. (1997). Localised dissolution kinetics, salt films and pitting potentials. Corrosion Science, 39(10-11), 1771-1790. doi:10.1016/s0010-938x(97)00049-8 es_ES
dc.description.references Moayed, M. H., & Newman, R. C. (2006). The Relationship Between Pit Chemistry and Pit Geometry Near the Critical Pitting Temperature. Journal of The Electrochemical Society, 153(8), B330. doi:10.1149/1.2210670 es_ES
dc.description.references Ernst, P., & Newman, R. . (2002). Pit growth studies in stainless steel foils. I. Introduction and pit growth kinetics. Corrosion Science, 44(5), 927-941. doi:10.1016/s0010-938x(01)00133-0 es_ES
dc.description.references Ernst, P., Laycock, N. J., Moayed, M. H., & Newman, R. C. (1997). The mechanism of lacy cover formation in pitting. Corrosion Science, 39(6), 1133-1136. doi:10.1016/s0010-938x(97)00043-7 es_ES
dc.description.references Sun, D., Jiang, Y., Tang, Y., Xiang, Q., Zhong, C., Liao, J., & Li, J. (2009). Pitting corrosion behavior of stainless steel in ultrasonic cell. Electrochimica Acta, 54(5), 1558-1563. doi:10.1016/j.electacta.2008.09.056 es_ES
dc.description.references Ren, J., & Zuo, Y. (2005). The growth mechanism of pits in NaCl solution under anodic films on aluminum. Surface and Coatings Technology, 191(2-3), 311-316. doi:10.1016/j.surfcoat.2004.04.054 es_ES


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