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Highly effective activation of aryl chlorides for Suzuki coupling in aqueous media using a ferrocene-based Pd(II) diimine catalyst

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Highly effective activation of aryl chlorides for Suzuki coupling in aqueous media using a ferrocene-based Pd(II) diimine catalyst

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dc.contributor.author Hanhan, Emre Murat es_ES
dc.contributor.author Martínez Mañez, Ramón es_ES
dc.contributor.author Ros-Lis, José Vicente es_ES
dc.date.accessioned 2016-02-22T12:32:23Z
dc.date.available 2016-02-22T12:32:23Z
dc.date.issued 2012-05-09
dc.identifier.issn 0040-4039
dc.identifier.uri http://hdl.handle.net/10251/61062
dc.description.abstract The Suzuki coupling of aryl chlorides with boronic acids using a ferrocene-containing Pd(II)-diimine complex as catalyst, in aqueous media, under microwave heating is reported. A small amount of the catalyst (0.1%) was found to be highly effective for coupling unactivated aryl chlorides with boronic acids to form sterically hindered ortho-substituted biaryls. The same catalyst also enabled the coupling of aryl bromides and iodides with various boronic acids in very high yields. The catalyst is air stable and the catalytic reaction can be completed in 15 min. © 2012 Elsevier Ltd. All rights reserved. es_ES
dc.description.sponsorship The authors thank the Research Board of Zonguldak Karaelmas University (BAP-2010-13-02-02, BAP-2011-10-03-11 and BAP-2011-10-03-012), the Spanish Government (projects MAT2009-14564-C01) and the Generalitat Valenciana (project PROMETEO/2009/016) for support. en_EN
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Tetrahedron Letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Aryl chlorides es_ES
dc.subject Green chemistry es_ES
dc.subject Microwave irradiation es_ES
dc.subject Pd(II) complexes es_ES
dc.subject Suzuki coupling es_ES
dc.subject Boronic acid derivative es_ES
dc.subject Ferrocene derivative es_ES
dc.subject Imine es_ES
dc.subject Palladium complex es_ES
dc.subject Polycyclic aromatic hydrocarbon derivative es_ES
dc.subject Aqueous solution es_ES
dc.subject Article es_ES
dc.subject Catalysis es_ES
dc.subject Catalyst es_ES
dc.subject Chemical structure es_ES
dc.subject Reaction time es_ES
dc.subject Stereospecificity es_ES
dc.subject Structure analysis es_ES
dc.subject Suzuki reaction es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Highly effective activation of aryl chlorides for Suzuki coupling in aqueous media using a ferrocene-based Pd(II) diimine catalyst es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.tetlet.2012.02.102
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2009%2F016/ES/Ayuda prometeo 2009 para el grupo de diseño y desarrollo de sensores/
dc.relation.projectID info:eu-repo/grantAgreement/ZBEU//BAP-2010-13-02-02/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ZBEU//BAP-2011-10-03-012/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ZBEU//BAP-2011-10-03-11/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2009-14564-C04-01/ES/Nanomateriales Hibridos Para El Desarrollo De "Puertas Moleculares" De Aplicacion En Procesos De Reconocimiento Y Terapeutica Y Para La Deteccion De Explosivos/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Hanhan, EM.; Martínez Mañez, R.; Ros-Lis, JV. (2012). Highly effective activation of aryl chlorides for Suzuki coupling in aqueous media using a ferrocene-based Pd(II) diimine catalyst. Tetrahedron Letters. 53(19):2388-2391. https://doi.org/10.1016/j.tetlet.2012.02.102 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.tetlet.2012.02.102 es_ES
dc.description.upvformatpinicio 2388 es_ES
dc.description.upvformatpfin 2391 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 53 es_ES
dc.description.issue 19 es_ES
dc.relation.senia 232799 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Zonguldak Bülent Ecevit University es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES


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