- -

Ring splitting of azetidin-2-ones via radical anions

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

Ring splitting of azetidin-2-ones via radical anions

Show full item record

Pérez Ruiz, R.; Sáez Cases, JA.; Domingo, LR.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2012). Ring splitting of azetidin-2-ones via radical anions. Organic and Biomolecular Chemistry. 10(39):7928-7932. doi:10.1039/c2ob26528a

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/61121

Files in this item

Item Metadata

Title: Ring splitting of azetidin-2-ones via radical anions
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
The radical anions of azetidin-2-ones, generated by UV-irradiation in the presence of triethylamine, undergo ring-splitting via N-C4 or C3-C4 bond breaking, leading to open-chain amides. This reactivity diverges from that ...[+]
Subjects: POLARIZABLE CONTINUUM MODEL , BETA-LACTAM RING , N-(ARYLIDENE(OR ALKYLIDENE)AMINO)-2-AZETIDINONES , STEREOCONTROLLED SYNTHESIS , STEREOSELECTIVE-SYNTHESIS , PHOTOCHEMICAL-REACTIONS , BUILDING-BLOCKS , DNA PHOTOLYASE , VINYL ETHERS , AZETIDINES
Copyrigths: Reserva de todos los derechos
Source:
Organic and Biomolecular Chemistry. (issn: 1477-0520 ) (eissn: 1477-0539 )
DOI: 10.1039/c2ob26528a
Publisher:
Royal Society of Chemistry
Publisher version: http://dx.doi.org/10.1039/c2ob26528a
Thanks:
Financial support from the MICINN (Grants CTQ-2010-14882, CTQ-2009-13699 and JCI-2010-06204), Generalitat Valenciana (Prometeo 2008/90), from CSIC (JAEDOC 101-2011) and from the UPV (Grant No. 20100994 and MCI Program) is ...[+]
Type: Artículo

This item appears in the following Collection(s)

Show full item record