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Mild synthesis of mesoporous silica supported ruthenium nanoparticles as heterogeneous catalysts in oxidative Wittig coupling reactions

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Mild synthesis of mesoporous silica supported ruthenium nanoparticles as heterogeneous catalysts in oxidative Wittig coupling reactions

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dc.contributor.author Carrillo, Adela I. es_ES
dc.contributor.author Schmidt, Luciana C. es_ES
dc.contributor.author Marín García, Mª Luisa es_ES
dc.contributor.author Scaiano, Juan C. es_ES
dc.date.accessioned 2016-03-04T10:50:34Z
dc.date.available 2016-03-04T10:50:34Z
dc.date.issued 2014
dc.identifier.issn 2044-4753
dc.identifier.uri http://hdl.handle.net/10251/61428
dc.description.abstract A new efficient approach for the in situ synthesis of anchored ruthenium nanoparticles (RuNP) in three different kinds of mesoporous silica materials, MCM-41, SBA-15 and HMS, has been developed. Solids have been synthesized under very mild conditions from RuCl3 center dot H2O salt reduced in one hour at room temperature in the mesoporous silicas previously grafted with aminopropyltriethoxysilane (APTES). Well-dispersed ruthenium nanoparticles, with an average size of 3 nm, anchored into the silica network by the APTES were obtained. These materials, with a molar ratio of Si/Ru = 40, were found to be catalytically active and selective in the alcohol oxidation-Wittig olefination. Interestingly, while the reaction occurs from the alcohol, control experiments suggest that the aldehyde (the common Wittig substrate) is not involved. es_ES
dc.description.sponsorship Thanks are due to the Natural Sciences and Engineering Council of Canada and the Canadian Foundation for Innovation for their generous support. M.L. Marin thanks the Universitat Politecnica de Valencia (Programa de Apoyo a la Investigacion y Desarrollo) for its financial support. Thanks are due to Dr. Yun Liu for advice on XPS interpretation. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science and Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject FISCHER-TROPSCH SYNTHESIS es_ES
dc.subject C BOND FORMATION es_ES
dc.subject BORROWING HYDROGEN es_ES
dc.subject GOLD NANOPARTICLES es_ES
dc.subject MOLECULAR-SIEVES es_ES
dc.subject ALCOHOLS es_ES
dc.subject FRAMEWORK es_ES
dc.subject EXCHANGE es_ES
dc.subject SBA-15 es_ES
dc.subject XPS es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Mild synthesis of mesoporous silica supported ruthenium nanoparticles as heterogeneous catalysts in oxidative Wittig coupling reactions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c3cy00773a
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Carrillo, AI.; Schmidt, LC.; Marín García, ML.; Scaiano, JC. (2014). Mild synthesis of mesoporous silica supported ruthenium nanoparticles as heterogeneous catalysts in oxidative Wittig coupling reactions. Catalysis Science and Technology. 4(2):435-440. doi:10.1039/c3cy00773a es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c3cy00773a es_ES
dc.description.upvformatpinicio 435 es_ES
dc.description.upvformatpfin 440 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 4 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 279826 es_ES
dc.identifier.eissn 2044-4761
dc.contributor.funder Natural Sciences and Engineering Research Council of Canada es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Canada Foundation for Innovation es_ES
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