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'From the mole to the molecule': ruthenium catalyzed nitroarene reduction studied with 'bench', high-throughput and single molecule fluorescence techniques

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'From the mole to the molecule': ruthenium catalyzed nitroarene reduction studied with 'bench', high-throughput and single molecule fluorescence techniques

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dc.contributor.author Carrillo, Adela I. es_ES
dc.contributor.author Stamplecoskie, Kevin G. es_ES
dc.contributor.author Marín García, Mª Luisa es_ES
dc.contributor.author Scaiano, Juan C. es_ES
dc.date.accessioned 2016-03-04T11:21:20Z
dc.date.available 2016-03-04T11:21:20Z
dc.date.issued 2014
dc.identifier.issn 2044-4753
dc.identifier.uri http://hdl.handle.net/10251/61429
dc.description.abstract Single molecule fluorescence microscopy techniques are used to complement conventional catalysis and high-throughput experiments in order to gain a complete picture of a model reaction. In these experiments a model nitroarene is reduced to an amine where, upon reduction, a red shift in absorption/emission, as well as an increase in emission, is observed. The reaction is studied under bulk reaction conditions by NMR spectroscopy and the fluorescence activation makes it possible to also study this reaction at the single molecule level. Fluorescence correlation spectroscopy is a valuable technique in supporting the proposed reaction mechanism and understanding the nature and duration of molecular 'visits' to catalytic sites, where both the starting material, nitroarene, and the amine product have an affinity for the catalyst. es_ES
dc.description.sponsorship Thanks are due to the Natural Sciences and Engineering Council of Canada and the Canadian Foundation for Innovation for generous support. M. L. Marin thanks the Universitat Politecnica de Valencia (Programa de Apoyo a la Investigacion y Desarrollo) for financial support. Technical support from Roxanne Clement at uOttawa's Centre for Catalysis Research and Innovation is gratefully acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science and Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject HETEROGENEOUS CATALYSTS es_ES
dc.subject GOLD NANOPARTICLES es_ES
dc.subject COUPLING REACTIONS es_ES
dc.subject REACTIVITY es_ES
dc.subject COMPLEXES es_ES
dc.subject ARYLATION es_ES
dc.subject DYNAMICS es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title 'From the mole to the molecule': ruthenium catalyzed nitroarene reduction studied with 'bench', high-throughput and single molecule fluorescence techniques es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c4cy00018h
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto Tecnológico de Informática - Institut Universitari Mixt Tecnològic d'Informàtica es_ES
dc.description.bibliographicCitation Carrillo, AI.; Stamplecoskie, KG.; Marín García, ML.; Scaiano, JC. (2014). 'From the mole to the molecule': ruthenium catalyzed nitroarene reduction studied with 'bench', high-throughput and single molecule fluorescence techniques. Catalysis Science and Technology. 4(7):1989-1996. doi:10.1039/c4cy00018h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c4cy00018h es_ES
dc.description.upvformatpinicio 1989 es_ES
dc.description.upvformatpfin 1996 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 4 es_ES
dc.description.issue 7 es_ES
dc.relation.senia 279827 es_ES
dc.identifier.eissn 2044-4761
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Natural Sciences and Engineering Research Council of Canada es_ES
dc.contributor.funder Canada Foundation for Innovation es_ES
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