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Biomass-Derived Chemicals: Synthesis of Biodegradable Surfactant Ether Molecules from Hydroxymethylfurfural

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Biomass-Derived Chemicals: Synthesis of Biodegradable Surfactant Ether Molecules from Hydroxymethylfurfural

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dc.contributor.author Arias Carrascal, Karen Sulay es_ES
dc.contributor.author Climent Olmedo, María José es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Iborra Chornet, Sara es_ES
dc.date.accessioned 2016-03-30T09:05:08Z
dc.date.issued 2014-02
dc.identifier.issn 1864-5631
dc.identifier.uri http://hdl.handle.net/10251/62077
dc.description.abstract A new class of biodegradable anionic surfactants with structures based on 5-alkoxymethylfuroate was prepared starting from 5-hydroxymethylfurfural (HMF), through a one-pot-two-steps process which involves the selective etherification of HMF with fatty alcohols using heterogeneous solid acid, followed by a highly selective oxidation of the formyl group with a gold catalyst. The etherification step was optimized using aluminosilicates as acid catalysts with different pore topologies (H-Beta, HY, Mordenite, ZSM-5, ITQ-2, and MCM-41), different active sites (Bronsted or Lewis) and different adsorption properties. It was shown that highly hydrophobic defect-free H-Beta zeolites with Si/Al ratios higher than 25 are excellent acid catalysts to perform the selective etherification of HMF with fatty alcohols, avoiding the competitive self-etherification of HMF. Moreover, the 5-alkoxymethylfurfural derivatives obtained can be selectively oxidized to the corresponding furoic salts in excellent yield using Au/CeO2 as catalyst and air as oxidant, at moderated temperatures. Both H-Beta zeolite and Au/CeO2 could be reused several times without loss of activity. es_ES
dc.description.sponsorship The authors acknowledge the Spanish Ministry of Education and Science for the financial support in the project Consolider-Ingenio 2010 and CTQ.-2011-27550. K. S. A. thanks Universidad Politecnica de Valencia and ITQ for FPI fellowships. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof ChemSusChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject 5-hydroxymethylfurfural es_ES
dc.subject biomass es_ES
dc.subject heterogeneous catalysis es_ES
dc.subject surfactants es_ES
dc.subject zeolites es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Biomass-Derived Chemicals: Synthesis of Biodegradable Surfactant Ether Molecules from Hydroxymethylfurfural es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cssc.201300531
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2011-27550/ES/TRANSFORMACION CATALITICA DE BIOMASA EN DIESEL Y EN PRODUCTOS QUIMICOS/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Arias Carrascal, KS.; Climent Olmedo, MJ.; Corma Canós, A.; Iborra Chornet, S. (2014). Biomass-Derived Chemicals: Synthesis of Biodegradable Surfactant Ether Molecules from Hydroxymethylfurfural. ChemSusChem. 7(1):210-220. https://doi.org/10.1002/cssc.201300531 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cssc.201300531 es_ES
dc.description.upvformatpinicio 210 es_ES
dc.description.upvformatpfin 220 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 7 es_ES
dc.description.issue 1 es_ES
dc.relation.senia 249452 es_ES
dc.identifier.eissn 1864-564X
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Instituto de Tecnología Química UPV-CSIC es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
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