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Cycloreversion of beta-lactams via photoinduced electron transfer

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Cycloreversion of beta-lactams via photoinduced electron transfer

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Pérez Ruiz, R.; Sáez Cases, JA.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2014). Cycloreversion of beta-lactams via photoinduced electron transfer. Organic and Biomolecular Chemistry. 12(42):8428-8432. doi:10.1039/c4ob01416b

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/62110

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Title: Cycloreversion of beta-lactams via photoinduced electron transfer
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
The radical anions of beta-lactams, photogenerated in the presence of DABCO as an electron donor, undergo cycloreversion via N-C4 bond cleavage, back electron transfer and final C2-C3 bond cleavage, leading to olefins. The ...[+]
Subjects: PHOTOCHEMICAL-REACTIONS , MILLENNIUM , KINETICS
Copyrigths: Reserva de todos los derechos
Source:
Organic and Biomolecular Chemistry. (issn: 1477-0520 ) (eissn: 1477-0539 )
DOI: 10.1039/c4ob01416b
Publisher:
Royal Society of Chemistry
Publisher version: http://dx.doi.org/10.1039/c4ob01416b
Thanks:
Financial support from the Spanish Government (CTQ2013-47872-C2-1-P, SEV-2012-0267, BES-2011-043706, JCI-2010-06204), from CSIC (JAEDOC 101-2011 co-funded by FSE) and from the Generalitat Valenciana (PROMETEOII/2013/005) ...[+]
Type: Artículo

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