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Cycloreversion of beta-lactams via photoinduced electron transfer

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Cycloreversion of beta-lactams via photoinduced electron transfer

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Pérez Ruiz, R.; Sáez Cases, JA.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2014). Cycloreversion of beta-lactams via photoinduced electron transfer. Organic and Biomolecular Chemistry. 12(42):8428-8432. https://doi.org/10.1039/c4ob01416b

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Título: Cycloreversion of beta-lactams via photoinduced electron transfer
Autor: Pérez Ruiz, Raul Sáez Cases, José Antonio Jiménez Molero, María Consuelo Miranda Alonso, Miguel Ángel
Entidad UPV: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Fecha difusión:
Resumen:
The radical anions of beta-lactams, photogenerated in the presence of DABCO as an electron donor, undergo cycloreversion via N-C4 bond cleavage, back electron transfer and final C2-C3 bond cleavage, leading to olefins. The ...[+]
Palabras clave: PHOTOCHEMICAL-REACTIONS , MILLENNIUM , KINETICS
Derechos de uso: Reserva de todos los derechos
Fuente:
Organic and Biomolecular Chemistry. (issn: 1477-0520 ) (eissn: 1477-0539 )
DOI: 10.1039/c4ob01416b
Editorial:
Royal Society of Chemistry
Versión del editor: http://dx.doi.org/10.1039/c4ob01416b
Código del Proyecto:
info:eu-repo/grantAgreement/MINECO//CTQ2013-47872-C2-1-P/ES/METABOLITOS FOTOACTIVOS/ /
...[+]
info:eu-repo/grantAgreement/MINECO//CTQ2013-47872-C2-1-P/ES/METABOLITOS FOTOACTIVOS/ /
info:eu-repo/grantAgreement/CSIC//JAEDOC 101-2011/
info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2013%2F005/ES/ESPECIES FOTOACTIVAS Y SU INTERACCION CON BIOMOLECULAS/
info:eu-repo/grantAgreement/MICINN//JCI-2010-06204/ES/JCI-2010-06204/
info:eu-repo/grantAgreement/MICINN//BES-2011-043706/ES/BES-2011-043706/
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ES/SEV-2012-0267/
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Agradecimientos:
Financial support from the Spanish Government (CTQ2013-47872-C2-1-P, SEV-2012-0267, BES-2011-043706, JCI-2010-06204), from CSIC (JAEDOC 101-2011 co-funded by FSE) and from the Generalitat Valenciana (PROMETEOII/2013/005) ...[+]
Tipo: Artículo

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