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Cycloreversion of beta-lactams via photoinduced electron transfer

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Cycloreversion of beta-lactams via photoinduced electron transfer

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dc.contributor.author Pérez Ruiz, Raul es_ES
dc.contributor.author Sáez Cases, José Antonio es_ES
dc.contributor.author Jiménez Molero, María Consuelo es_ES
dc.contributor.author Miranda Alonso, Miguel Ángel es_ES
dc.date.accessioned 2016-04-01T10:55:11Z
dc.date.available 2016-04-01T10:55:11Z
dc.date.issued 2014-11-14
dc.identifier.issn 1477-0520
dc.identifier.uri http://hdl.handle.net/10251/62110
dc.description.abstract The radical anions of beta-lactams, photogenerated in the presence of DABCO as an electron donor, undergo cycloreversion via N-C4 bond cleavage, back electron transfer and final C2-C3 bond cleavage, leading to olefins. The involved intermediates are 1,4-radical anions and 1,4-biradicals. The experimental observations are consistent with the results of DFT calculations. es_ES
dc.description.sponsorship Financial support from the Spanish Government (CTQ2013-47872-C2-1-P, SEV-2012-0267, BES-2011-043706, JCI-2010-06204), from CSIC (JAEDOC 101-2011 co-funded by FSE) and from the Generalitat Valenciana (PROMETEOII/2013/005) is gratefully acknowledged. J. A. S. acknowledges the computational facilities provided by the Theoretical Computational Chemistry Group of Prof. L. R. Domingo at the Universitat de Valencia. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Organic and Biomolecular Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject PHOTOCHEMICAL-REACTIONS es_ES
dc.subject MILLENNIUM es_ES
dc.subject KINETICS es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Cycloreversion of beta-lactams via photoinduced electron transfer es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c4ob01416b
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2013-47872-C2-1-P/ES/METABOLITOS FOTOACTIVOS/ / es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CSIC//JAEDOC 101-2011/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2013%2F005/ES/ESPECIES FOTOACTIVAS Y SU INTERACCION CON BIOMOLECULAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//JCI-2010-06204/ES/JCI-2010-06204/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//BES-2011-043706/ES/BES-2011-043706/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ES/SEV-2012-0267/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Pérez Ruiz, R.; Sáez Cases, JA.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2014). Cycloreversion of beta-lactams via photoinduced electron transfer. Organic and Biomolecular Chemistry. 12(42):8428-8432. https://doi.org/10.1039/c4ob01416b es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c4ob01416b es_ES
dc.description.upvformatpinicio 8428 es_ES
dc.description.upvformatpfin 8432 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 42 es_ES
dc.relation.senia 288000 es_ES
dc.identifier.eissn 1477-0539
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
dc.contributor.funder European Social Fund es_ES
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