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MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst

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MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst

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dc.contributor.author García Cirujano, Francisco es_ES
dc.contributor.author Llabrés i Xamena, Francesc Xavier es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2016-04-11T12:44:15Z
dc.date.available 2016-04-11T12:44:15Z
dc.date.issued 2012
dc.identifier.issn 1477-9226
dc.identifier.uri http://hdl.handle.net/10251/62423
dc.description.abstract A bifunctional MOF catalyst containing coordinatively unsaturated Cr3+ sites and palladium nanoparticles (Pd@MIL-101) has been used for the cyclization of citronellal to isopulegol and for the one-pot tandem isomerization/hydrogenation of citronellal to menthol. The MOF was found to be stable under the reaction conditions used, and the results obtained indicate that the performance of this bifunctional solid catalyst is comparable with other state-of-the-art materials for the tandem reaction: Full citronellal conversion was attained over Pd@MIL-101 in 18 h, with 86% selectivity to menthols and a diastereoselectivity of 81% to the desired (-)-menthol, while up to 30 h were necessary for attaining similar values over Ir/H-beta under analogous reaction conditions. es_ES
dc.description.sponsorship Financial support by Ministerio de Educacion y Ciencia e Innovacion (Project MIYCIN, CSD2009-00050; PROGRAMA CONSOLIDER. INGENIO 2009), Generalidad Valenciana (GV PROMETEO/2008/130) and the CSIC (Proyectos Intramurales Especiales 201080I020) is gratefully acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Dalton Transactions es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject METAL-ORGANIC FRAMEWORKS es_ES
dc.subject IR-BETA ZEOLITE es_ES
dc.subject HETEROGENEOUS CATALYST es_ES
dc.subject ACID es_ES
dc.subject LEWIS es_ES
dc.subject TRANSFORMATION es_ES
dc.subject CARBOXYLATE es_ES
dc.subject SITES es_ES
dc.subject WATER es_ES
dc.subject STEP es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c2dt12480g
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Generalitat Valenciana//PROMETEO08%2F2008%2F130/ES/Química sostenible: Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CSIC//201080I020/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation García Cirujano, F.; Llabrés I Xamena, FX.; Corma Canós, A. (2012). MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst. Dalton Transactions. 41:4249-4254. https://doi.org/10.1039/c2dt12480g es_ES
dc.description.accrualMethod S es_ES
dc.description.upvformatpinicio 4249 es_ES
dc.description.upvformatpfin 4254 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 41 es_ES
dc.relation.senia 244271 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
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