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Graphenes as Metal-free Catalysts for the Oxidative Depolymerization of Lignin Models

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Graphenes as Metal-free Catalysts for the Oxidative Depolymerization of Lignin Models

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dc.contributor.author Blandez Barradas, Juan Francisco es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2016-05-10T08:54:14Z
dc.date.issued 2015-09-14
dc.identifier.issn 1867-3880
dc.identifier.uri http://hdl.handle.net/10251/63835
dc.description.abstract Graphene oxide promotes the oxidative degradation of -guaiacylglycerol--guaiacyl ether, a lignin model compound, in different solvents including acetonitrile, toluene and water mainly to guaiacol, 2-methoxyquinone, vanillic acid and coniferyl aldehyde. Reduced graphene oxide and B-doped graphene exhibit similar activity as graphene oxide. Control experiments indicate that metal impurities should play a marginal role in the observed catalytic activity. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and Generalitat Valenciana (Prometeo 2012-013) is gratefully acknowledged. Partial financial support by the European Union (Novacam project) is also acknowledged. J. F. B. thanks to the Technical University of Valencia for a PhD scholarship. en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation Spanish Ministry of Economy and Competitiveness CTQ2012-32315 es_ES
dc.relation Generalitat Valenciana Prometeo 2012-013 es_ES
dc.relation European Union (Novacam project) es_ES
dc.relation Technical University of Valencia es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Graphene es_ES
dc.subject Oxidn catalyst es_ES
dc.subject depolymn of lignin models es_ES
dc.subject carbocatalysis es_ES
dc.subject graphene as catalyst es_ES
dc.subject heterogeneous catalysis es_ES
dc.subject lignin depolymerization es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Graphenes as Metal-free Catalysts for the Oxidative Depolymerization of Lignin Models es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cctc.201500477
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Blandez Barradas, JF.; Navalón Oltra, S.; Alvaro Rodríguez, MM.; García Gómez, H. (2015). Graphenes as Metal-free Catalysts for the Oxidative Depolymerization of Lignin Models. ChemCatChem. 7(18):3020-3026. doi:10.1002/cctc.201500477 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cctc.201500477 es_ES
dc.description.upvformatpinicio 3020 es_ES
dc.description.upvformatpfin 3026 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 7 es_ES
dc.description.issue 18 es_ES
dc.relation.senia 298271 es_ES
dc.identifier.eissn 1867-3899


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