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Unique distal size selectivity with a digold catalyst during alkyne homocoupling

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Unique distal size selectivity with a digold catalyst during alkyne homocoupling

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Leyva Perez, A.; Domenech Carbo, A.; Corma Canós, A. (2015). Unique distal size selectivity with a digold catalyst during alkyne homocoupling. Nature Communications. 6. doi:10.1038/ncomms7703

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Title: Unique distal size selectivity with a digold catalyst during alkyne homocoupling
Author: Leyva Perez, Antonio Domenech Carbo, Antonio Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
Metal-catalysed chemical reactions are often controlled by steric hindrance around the metal atom and it is rare that substituents far away of the reaction site could be differentiated during reaction, particularly if they ...[+]
Subjects: HOMOGENEOUS GOLD CATALYSIS , C-H ACTIVATION , TERMINAL ALKYNES , COUPLING REACTIONS , COMPLEXES , TRANSMETALATION , ALKENES , CYCLIZATION , GOLD(III) , ACETYLIDE
Copyrigths: Reserva de todos los derechos
Source:
Nature Communications. (issn: 2041-1723 )
DOI: 10.1038/ncomms7703
Publisher:
Nature Publishing Group
Publisher version: http://dx.doi.org/10.1038/ncomms7703
Thanks:
Financial support by Consolider-Ingenio 2010 (proyecto MULTICAT) and Severo Ochoa programs from MCIINN and Prometeo program from Generalitat Valenciana is acknowledged. A. L.-P. thanks ITQ for the concession of a contract. ...[+]
Type: Artículo

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