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Segmental Poly(urethane-urea) elastomers based on polycaporlactone: structure and porperties

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Segmental Poly(urethane-urea) elastomers based on polycaporlactone: structure and porperties

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Nombre: LUIS MAY-HERNÁNDE ...
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dc.contributor.author May Hernandez, Luis Humberto es_ES
dc.contributor.author Hernandez Sanchez, Fernando es_ES
dc.contributor.author Gómez Ribelles, José Luís es_ES
dc.contributor.author Sabater i Serra, Roser es_ES
dc.date.accessioned 2016-05-17T06:17:11Z
dc.date.available 2016-05-17T06:17:11Z
dc.date.issued 2011
dc.identifier.issn 0021-8995
dc.identifier.uri http://hdl.handle.net/10251/64144
dc.description.abstract A series of segmented poly(urethane-urea) polymers have been synthesized varying the hard segments content, based on the combination of polycaprolactone diol and aliphatic diisocyanate (Bis(4-isocyanatocyclohexyl)methane), using diamine (1,4-Butylenediamine) as the chain extender. The microstructure and properties of the material highly depend on the hard segments content (from 14 to 40%). These PUUs with hard segment content above 23% have elastomeric behaviors that allow high recoverable deformation. The chemical structure and hydrogen bonding interactions were studied using FTIR and atomic force microscopy, which revealed phase separation that was also confirmed by DSC, dynamic-mechanical, and dielectric spectroscopy. © 2010 Wiley Periodicals, Inc. es_ES
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof Journal of Applied Polymer Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Block copolymers es_ES
dc.subject Elastomers es_ES
dc.subject Phase separation es_ES
dc.subject Poly(urethane-urea) es_ES
dc.subject Polycaprolactone es_ES
dc.subject Aliphatic diisocyanate es_ES
dc.subject Chain extenders es_ES
dc.subject Chemical structure es_ES
dc.subject Elastomeric behavior es_ES
dc.subject FTIR es_ES
dc.subject Hard segments es_ES
dc.subject Hydrogen bonding interactions es_ES
dc.subject Microstructure and properties es_ES
dc.subject Polycaprolactone diols es_ES
dc.subject Structure and properties es_ES
dc.subject Atomic force microscopy es_ES
dc.subject Atomic spectroscopy es_ES
dc.subject Copolymerization es_ES
dc.subject Hydrogen bonds es_ES
dc.subject Metabolism es_ES
dc.subject Methane es_ES
dc.subject Plastics es_ES
dc.subject Urea es_ES
dc.subject.classification INGENIERIA ELECTRICA es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Segmental Poly(urethane-urea) elastomers based on polycaporlactone: structure and porperties es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/app.32929
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Eléctrica - Departament d'Enginyeria Elèctrica es_ES
dc.description.bibliographicCitation May Hernandez, LH.; Hernandez Sanchez, F.; Gómez Ribelles, JL.; Sabater I Serra, R. (2011). Segmental Poly(urethane-urea) elastomers based on polycaporlactone: structure and porperties. Journal of Applied Polymer Science. 119(4):2093-2104. doi:10.1002/app.32929 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/app.32929 es_ES
dc.description.upvformatpinicio 2093 es_ES
dc.description.upvformatpfin 2104 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 119 es_ES
dc.description.issue 4 es_ES
dc.relation.senia 206847 es_ES
dc.identifier.eissn 1097-4628
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