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Charge transfer, bonding conditioning and solvation effect in the activation of the oxygen reduction reaction on unclustered graphitic-nitrogen-doped graphene

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Charge transfer, bonding conditioning and solvation effect in the activation of the oxygen reduction reaction on unclustered graphitic-nitrogen-doped graphene

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dc.contributor.author Ferre Vilaplana, Adolfo es_ES
dc.contributor.author Herrero, Enrique es_ES
dc.date.accessioned 2016-05-17T08:47:01Z
dc.date.available 2016-05-17T08:47:01Z
dc.date.issued 2015-05
dc.identifier.issn 1463-9076
dc.identifier.uri http://hdl.handle.net/10251/64205
dc.description.abstract The monodentate associative chemisorption of molecular oxygen on unclustered graphitic-nitrogen-doped graphene requires two nitrogen dopants per activated molecule. Significant charge transfers fromregions corresponding to distant nitrogen-dopants, the presence of a nitrogen-dopant adjacent to the carbon atom acting as an active site, which favours its transition from a sp(2) hybridization state to sp(3), and the solvation effect turn the investigated mechanism to a favourable process es_ES
dc.description.sponsorship This work has been financially supported by the MICINN (Spain) (project 2013-44083-P) and Generalitat Valenciana (project PROMETEOII/2014/013). en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Physical Chemistry Chemical Physics es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject Carbon nanotubes es_ES
dc.subject Active-sites es_ES
dc.subject Impurities es_ES
dc.title Charge transfer, bonding conditioning and solvation effect in the activation of the oxygen reduction reaction on unclustered graphitic-nitrogen-doped graphene es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c5cp00918a
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2013-44083-P/ES/ESTUDIOS AVANZADOS SOBRE LA REACCION DE REDUCCION DE OXIGENO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2014%2F013/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto Tecnológico de Informática - Institut Universitari Mixt Tecnològic d'Informàtica es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Sistemas Informáticos y Computación - Departament de Sistemes Informàtics i Computació es_ES
dc.description.bibliographicCitation Ferre Vilaplana, A.; Herrero, E. (2015). Charge transfer, bonding conditioning and solvation effect in the activation of the oxygen reduction reaction on unclustered graphitic-nitrogen-doped graphene. Physical Chemistry Chemical Physics. 17(25):16238-16242. https://doi.org/10.1039/c5cp00918a es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c5cp00918a es_ES
dc.description.upvformatpinicio 16238 es_ES
dc.description.upvformatpfin 16242 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 17 es_ES
dc.description.issue 25 es_ES
dc.relation.senia 291649 es_ES
dc.identifier.eissn 1463-9084
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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