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Biodegradable poly(L-lactide) and polycaprolactone block copolymer networks

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Biodegradable poly(L-lactide) and polycaprolactone block copolymer networks

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dc.contributor.author Escobar Ivirico, Jorge Luis es_ES
dc.contributor.author Salmerón Sánchez, Manuel es_ES
dc.contributor.author Gómez Ribelles, José Luís es_ES
dc.contributor.author Monleón Pradas, Manuel es_ES
dc.date.accessioned 2016-05-17T09:15:03Z
dc.date.available 2016-05-17T09:15:03Z
dc.date.issued 2011
dc.identifier.issn 0959-8103
dc.identifier.uri http://hdl.handle.net/10251/64209
dc.description.abstract New biodegradable block copolymer networks were synthesized from methacrylate-terminated poly(L-lactide) (mLA) and polycaprolactone (mCL) macromers. This allowed the realization of a series of materials in which the macromer ratio can be used to tailor the physical and mechanical properties of the materials. The synthesis of the macromers was characterized using Fourier transform infrared (FTIR) spectroscopy and 1H NMR spectroscopy. Poly(mCL) and poly(mLA) networks were prepared by photopolymerization of the macromers, and copolymers were also prepared from the two macromers in various proportions. The phase microstructure of the new systems and the network architecture were investigated using differential scanning calorimetry, FTIR spectroscopy, dynamic mechanical analysis and thermogravimetry studies. Ideal structure, compatible with the experiments results, for biodegradable poly(L-lactide) and polycaprolactone block copolymer networks. Copyright © 2010 Society of Chemical Industry. es_ES
dc.description.sponsorship The authors acknowledge the support of the Spanish Science & Innovation Ministry through project MAT2008-06434. JLEI acknowledge the support of Spanish Science & Innovation Ministry through the "Campus de Excelencia Internacional" program consistent with Polytechnic University of Valencia. The authors also acknowledge the support of CIBER-BBN which is an initiative funded by the VI National R&D&D&i Plan 2008 - 2011, Iniciativa Ingenio 2010, Consolider Program, CIBER Actions and financed by the Instituto de Salud Carlos III with assistance from the European Regional Development Fund and the funding by the Centro de Investigacion Principe Felipe in the field of regenerative medicine through the collaboration agreement from the Conselleria de Sanidad (Generalitat Valenciana) and the Instituto de Salud Carlos III (Ministry of Science and Innovation). en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof Polymer International es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Biodegradable es_ES
dc.subject Block copolymer es_ES
dc.subject Poly(L-lactide) es_ES
dc.subject Polycaprolactone es_ES
dc.subject Polyester es_ES
dc.subject Polymer network es_ES
dc.subject Biodegradable block copolymers es_ES
dc.subject Copolymer networks es_ES
dc.subject FTIR spectroscopy es_ES
dc.subject H NMR spectroscopy es_ES
dc.subject Macromer ratio es_ES
dc.subject Macromers es_ES
dc.subject New system es_ES
dc.subject Physical and mechanical properties es_ES
dc.subject Poly (l-lactide) es_ES
dc.subject Thermogravimetry es_ES
dc.subject Biodegradable polymers es_ES
dc.subject Block copolymers es_ES
dc.subject Copolymerization es_ES
dc.subject Differential scanning calorimetry es_ES
dc.subject Dynamic analysis es_ES
dc.subject Dynamic mechanical analysis es_ES
dc.subject Fourier transform infrared spectroscopy es_ES
dc.subject Fourier transforms es_ES
dc.subject Materials properties es_ES
dc.subject Mechanical properties es_ES
dc.subject Network architecture es_ES
dc.subject Nuclear magnetic resonance spectroscopy es_ES
dc.subject Photopolymerization es_ES
dc.subject Plastic products es_ES
dc.subject Thermogravimetric analysis es_ES
dc.subject Organic polymers es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Biodegradable poly(L-lactide) and polycaprolactone block copolymer networks es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/pi.2938
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2008-06434/ES/MATERIALES PARA REGENERACION NEURAL Y ANGIOGENESIS EN EL SISTEMA NERVIOSO CENTRAL/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Centro de Biomateriales e Ingeniería Tisular - Centre de Biomaterials i Enginyeria Tissular es_ES
dc.description.bibliographicCitation Escobar Ivirico, JL.; Salmerón Sánchez, M.; Gómez Ribelles, JL.; Monleón Pradas, M. (2011). Biodegradable poly(L-lactide) and polycaprolactone block copolymer networks. Polymer International. 60(2):264-270. https://doi.org/10.1002/pi.2938 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/pi.2938 es_ES
dc.description.upvformatpinicio 264 es_ES
dc.description.upvformatpfin 270 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 60 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 191788 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Centro de Investigación Príncipe Felipe es_ES
dc.contributor.funder Instituto de Salud Carlos III es_ES
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