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Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream

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Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream

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dc.contributor.author Arias Carrascal, Karen Sulay es_ES
dc.contributor.author Climent Olmedo, María José es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Iborra Chornet, Sara es_ES
dc.date.accessioned 2016-06-02T11:37:18Z
dc.date.available 2016-06-02T11:37:18Z
dc.date.issued 2015
dc.identifier.issn 1754-5692
dc.identifier.uri http://hdl.handle.net/10251/65116
dc.description.abstract Alkylation of aromatics with HMF is a new route for the synthesis of biofuels. Alkylation of toluene with HMF has been studied in the presence of large pore (HBeta, USY and Mordenite), delaminated zeolites as well as on mesoporous aluminosilicates. In all cases a mixture of monoalkylated products of 5-(o-, m- and p-methyl)benzylfuran-2-carbaldehyde and OBMF coming from self etherification of HMF were obtained. Large pore 3D (USY) and especially 2D (ITQ-2) zeolites are active and selective catalysts for this transformation. The alkylation reaction was extended successfully to other substituted benzenes as well as to a heavy reformate mixture as source aromatic compounds, achieving 91% yield of alkylated products with 93% selectivity. Further hydrodeoxygenation of alkylated compounds in a fixed bed continuous reactor was performed using Pt/C and Pt/TiO2 as catalysts allowing to obtain a hydrocarbon mixture containing alkylcyclohexane compounds that can be used as high quality kerosene. es_ES
dc.description.sponsorship Financial support by Consolider-Ingenio 2010 (project MULTICAT), Spanish MICINN Project CTQ-2011-27550), Generalitat Valenciana (Prometeo program) and Program Severo Ochoa are gratefully acknowledged. This work was supported by Consolider. KSA is grateful to ITQ for a doctoral grant. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation Consolider-Ingenio (project MULTICAT) es_ES
dc.relation Spanish MICINN Project CTQ-2011-27550 es_ES
dc.relation Generalitat Valenciana (Prometeo program) es_ES
dc.relation Program Severo Ochoa es_ES
dc.relation Consolider es_ES
dc.relation ITQ es_ES
dc.relation.ispartof Energy and Environmental Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject HIERARCHICAL ZEOLITE CATALYSTS es_ES
dc.subject FRIEDEL-CRAFTS ALKYLATION es_ES
dc.subject TRANSPORTATION FUELS es_ES
dc.subject PLATFORM MOLECULES es_ES
dc.subject AROMATIC-COMPOUNDS es_ES
dc.subject D-FRUCTOSE es_ES
dc.subject DIESEL es_ES
dc.subject ACID es_ES
dc.subject CONVERSION es_ES
dc.subject MECHANISM es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c4ee03194f
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Arias Carrascal, KS.; Climent Olmedo, MJ.; Corma Canós, A.; Iborra Chornet, S. (2015). Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream. Energy and Environmental Science. 8(1):317-331. doi:10.1039/c4ee03194f es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c4ee03194f es_ES
dc.description.upvformatpinicio 317 es_ES
dc.description.upvformatpfin 331 es_ES
dc.type.version info:eu repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 1 es_ES
dc.relation.senia 297467 es_ES
dc.identifier.eissn 1754-5706


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