dc.contributor.author |
Gianotti, Enrica
|
es_ES |
dc.contributor.author |
Díaz Morales, Urbano Manuel
|
es_ES |
dc.contributor.author |
Velty, Alexandra
|
es_ES |
dc.contributor.author |
Corma Canós, Avelino
|
es_ES |
dc.date.accessioned |
2016-06-17T12:02:25Z |
|
dc.date.available |
2016-06-17T12:02:25Z |
|
dc.date.issued |
2013 |
|
dc.identifier.issn |
2044-4753 |
|
dc.identifier.uri |
http://hdl.handle.net/10251/66091 |
|
dc.description.abstract |
[EN] Bifunctional mesoporous hybrid materials, containing both proton sponges and acid groups, have been prepared following different synthetic routes: co-condensation processes (sol-gel or micellar one-pot routes) or post-synthetic grafting of the organic functionalities. 1,8-Bis(dimethylamino)naphthalene (DMAN), a proton sponge with high pK(a), was used as an organic functional builder base and 3-mercaptopropyltriethoxysilane (MPTES) as a pendant precursor of sulfonic acids. The bifunctional hybrid materials were extensively characterized and were investigated as heterogeneous catalysts for various one-pot C-C bond-forming cascade reactions such as deacetalization-Knoevenagel condensation or deacetalization-nitroaldol (Henry) reaction. |
es_ES |
dc.description.sponsorship |
The authors thank the Spanish Government for financial support by Consolider-Ingenio MULTICAT CSD2009-00050, MAT2011-29020-C02-01 and Severo Ochoa Excellence Program SEV-2012-0267. EG thanks the Marie Curie Fellowship (FP7-PEOPLE-2009-IEF) for financial support. |
en_EN |
dc.language |
Inglés |
es_ES |
dc.publisher |
Royal Society of Chemistry |
es_ES |
dc.relation |
MICINN/CSD2009-00050 |
es_ES |
dc.relation |
MICINN/MAT2011-29020-C02-01 |
es_ES |
dc.relation |
MINECO/SEV-2012-0267 |
|
dc.relation.ispartof |
Catalysis Science and Technology |
es_ES |
dc.rights |
Reserva de todos los derechos |
es_ES |
dc.subject |
Bond-forming reactions |
es_ES |
dc.subject |
Silica nanoparticles |
es_ES |
dc.subject |
Molecular-sieves |
es_ES |
dc.subject |
Henry Reaction |
es_ES |
dc.subject |
Organosilica |
es_ES |
dc.subject |
Inhibitors |
es_ES |
dc.subject |
System |
es_ES |
dc.subject |
Condensation |
es_ES |
dc.subject |
Selectivity |
es_ES |
dc.subject |
Strategies |
es_ES |
dc.subject.classification |
QUIMICA ORGANICA |
es_ES |
dc.title |
Designing bifunctional acid-base mesoporous hybrid catalysts for cascade reactions |
es_ES |
dc.type |
Artículo |
es_ES |
dc.identifier.doi |
10.1039/c3cy00269a |
|
dc.relation.projectID |
info:eu-repo/grantAgreement/EC/FP7/252367 |
|
dc.rights.accessRights |
Abierto |
es_ES |
dc.contributor.affiliation |
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química |
es_ES |
dc.contributor.affiliation |
Universitat Politècnica de València. Departamento de Química - Departament de Química |
es_ES |
dc.description.bibliographicCitation |
Gianotti, E.; Díaz Morales, UM.; Velty, A.; Corma Canós, A. (2013). Designing bifunctional acid-base mesoporous hybrid catalysts for cascade reactions. Catalysis Science and Technology. 3(10):2677-2688. doi:10.1039/c3cy00269a |
es_ES |
dc.description.accrualMethod |
Senia |
es_ES |
dc.relation.publisherversion |
http://dx.doi.org/10.1039/c3cy00269a |
es_ES |
dc.description.upvformatpinicio |
2677 |
es_ES |
dc.description.upvformatpfin |
2688 |
es_ES |
dc.type.version |
info:eu-repo/semantics/publishedVersion |
es_ES |
dc.description.volume |
3 |
es_ES |
dc.description.issue |
10 |
es_ES |
dc.relation.senia |
258359 |
es_ES |
dc.contributor.funder |
European Commission |
|
dc.contributor.funder |
Ministerio de Ciencia e Innovación |
|
dc.contributor.funder |
Ministerio de Economía y Competitividad |
|