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dc.contributor.author | Gianotti, Enrica![]() |
es_ES |
dc.contributor.author | Díaz Morales, Urbano Manuel![]() |
es_ES |
dc.contributor.author | Velty, Alexandra![]() |
es_ES |
dc.contributor.author | Corma Canós, Avelino![]() |
es_ES |
dc.date.accessioned | 2016-06-17T12:02:25Z | |
dc.date.available | 2016-06-17T12:02:25Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 2044-4753 | |
dc.identifier.uri | http://hdl.handle.net/10251/66091 | |
dc.description.abstract | [EN] Bifunctional mesoporous hybrid materials, containing both proton sponges and acid groups, have been prepared following different synthetic routes: co-condensation processes (sol-gel or micellar one-pot routes) or post-synthetic grafting of the organic functionalities. 1,8-Bis(dimethylamino)naphthalene (DMAN), a proton sponge with high pK(a), was used as an organic functional builder base and 3-mercaptopropyltriethoxysilane (MPTES) as a pendant precursor of sulfonic acids. The bifunctional hybrid materials were extensively characterized and were investigated as heterogeneous catalysts for various one-pot C-C bond-forming cascade reactions such as deacetalization-Knoevenagel condensation or deacetalization-nitroaldol (Henry) reaction. | es_ES |
dc.description.sponsorship | The authors thank the Spanish Government for financial support by Consolider-Ingenio MULTICAT CSD2009-00050, MAT2011-29020-C02-01 and Severo Ochoa Excellence Program SEV-2012-0267. EG thanks the Marie Curie Fellowship (FP7-PEOPLE-2009-IEF) for financial support. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Catalysis Science and Technology | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Bond-forming reactions | es_ES |
dc.subject | Silica nanoparticles | es_ES |
dc.subject | Molecular-sieves | es_ES |
dc.subject | Henry Reaction | es_ES |
dc.subject | Organosilica | es_ES |
dc.subject | Inhibitors | es_ES |
dc.subject | System | es_ES |
dc.subject | Condensation | es_ES |
dc.subject | Selectivity | es_ES |
dc.subject | Strategies | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Designing bifunctional acid-base mesoporous hybrid catalysts for cascade reactions | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/c3cy00269a | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/252367/EU/Decomposition of Structured Tensors, Algorithms and Characterization./ | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-01/ES/CATALIZADORES HIBRIDOS MULTIFUNCIONALES BASADOS EN UNIDADES ESTRUCTURALES ORGANICAS-INORGANICAS UTILIZADOS EN REACCIONES CASCADA/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Gianotti, E.; Díaz Morales, UM.; Velty, A.; Corma Canós, A. (2013). Designing bifunctional acid-base mesoporous hybrid catalysts for cascade reactions. Catalysis Science and Technology. 3(10):2677-2688. https://doi.org/10.1039/c3cy00269a | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c3cy00269a | es_ES |
dc.description.upvformatpinicio | 2677 | es_ES |
dc.description.upvformatpfin | 2688 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 3 | es_ES |
dc.description.issue | 10 | es_ES |
dc.relation.senia | 258359 | es_ES |
dc.contributor.funder | European Commission | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | |
dc.contributor.funder | Ministerio de Economía y Competitividad | |
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