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Metal-containing zeolites as efficient catalyst for the transformation of highly valuable chiral biomass-derived products

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Metal-containing zeolites as efficient catalyst for the transformation of highly valuable chiral biomass-derived products

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dc.contributor.author Paris Carrizo, Cecilia Gertrudis es_ES
dc.contributor.author Moliner Marin, Manuel es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2016-07-11T09:32:00Z
dc.date.available 2016-07-11T09:32:00Z
dc.date.issued 2013
dc.identifier.issn 1463-9262
dc.identifier.uri http://hdl.handle.net/10251/67403
dc.description.abstract Metal-containing zeolites, especially Sn-Beta, perform as very efficient heterogeneous catalysts in the selective oxidation of levoglucosenone, which is considered as a platform chemical for the production of highly-valuable chemicals, towards the synthesis of the optically pure gamma-lactone(S)-gamma-hydroxymethyl-alpha,beta-butenolide (HBO) using H2O2 as an oxidizing agent. Using Sn-Beta as a catalyst, yields up to 75% of (S)-gamma-hydroxymethyl-alpha,beta-butenolide are achieved in a "one-pot" cascade reaction. When Sn-Beta is combined with an acid resin, such as Amberlyst-15, the "two-step" process allows yields up to 90%. es_ES
dc.description.sponsorship This work has been supported by the Spanish Government MINECO through Consolider Ingenio 2010-Multicat and MAT2012-37160, and by UPV through PAID-06-11 (n.1952). Manuel Moliner also acknowledges "Subprograma Ramon y Cajal" for contract RYC-2011-08972. ITQ thanks the "Program Severo Ochoa" for financial support. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Green Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject MEERWEIN-PONNDORF-VERLEY es_ES
dc.subject SOLID LEWIS-ACIDS es_ES
dc.subject SN-BETA ZEOLITES es_ES
dc.subject PROMISING METHOD es_ES
dc.subject FAST PYROLYSIS es_ES
dc.subject WATER es_ES
dc.subject ISOMERIZATION es_ES
dc.subject CONVERSION es_ES
dc.subject MECHANISM es_ES
dc.subject CHEMICALS es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Metal-containing zeolites as efficient catalyst for the transformation of highly valuable chiral biomass-derived products es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c3gc40267c
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-06-11-1952/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//RYC-2011-08972/ES/RYC-2011-08972/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2012-37160/ES/SINTESIS DE NUEVOS MATERIALES MICROPOROSOS BASADOS EN EL USO DE ?ESPONJAS DE PROTONES? COMO AGENTES DIRECTORES DE ESTRUCTURA (ADES)/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Paris Carrizo, CG.; Moliner Marin, M.; Corma Canós, A. (2013). Metal-containing zeolites as efficient catalyst for the transformation of highly valuable chiral biomass-derived products. Green Chemistry. 15(8):2101-2109. https://doi.org/10.1039/c3gc40267c es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c3gc40267c es_ES
dc.description.upvformatpinicio 2101 es_ES
dc.description.upvformatpfin 2109 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 15 es_ES
dc.description.issue 8 es_ES
dc.relation.senia 258030 es_ES
dc.identifier.eissn 1463-9270
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
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